TY - JOUR
T1 - 1,2-Bis(ferrocenyl)-substituted distibene and dibismuthene
T2 - Sb=Sb and Bi=Bi units as π spacers between two ferrocenyl units
AU - Sakagami, Michiyasu
AU - Sasamori, Takahiro
AU - Sakai, Heisuke
AU - Furukawa, Yukio
AU - Tokitoh, Norihiro
PY - 2013/4
Y1 - 2013/4
N2 - Pi in the sky: 1,2-bis(ferrocenyl)distibene and 1,2-bis(ferrocenyl) dibismuthene derivatives, where two bulky ferrocenyl units are bridged by a Sb=Sb and Bi=Bi π spacer, have been synthesized as a new family of novel d-π conjugated systems. Their molecular structures, spectroscopic behavior, and electrochemical properties reveal the Sb=Sb and Bi=Bi units to be effective π-electron spacers.
AB - Pi in the sky: 1,2-bis(ferrocenyl)distibene and 1,2-bis(ferrocenyl) dibismuthene derivatives, where two bulky ferrocenyl units are bridged by a Sb=Sb and Bi=Bi π spacer, have been synthesized as a new family of novel d-π conjugated systems. Their molecular structures, spectroscopic behavior, and electrochemical properties reveal the Sb=Sb and Bi=Bi units to be effective π-electron spacers.
KW - conjugation
KW - main-group elements
KW - pi interactions
KW - redox chemistry
KW - sandwich complexes
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U2 - 10.1002/asia.201201227
DO - 10.1002/asia.201201227
M3 - Article
C2 - 23377927
AN - SCOPUS:84875325772
SN - 1861-4728
VL - 8
SP - 690
EP - 693
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
IS - 4
ER -