3-Dithiolthione-substituted polythiophene and its redox activities

Ichiro Takemura; Tomokazu Iwasaki; Shinji Takeoka; Hiroyuki Nishide

doi:10.1246/cl.2004.1482

3-Dithiolthione-substituted polythiophene and its redox activities

Ichiro Takemura, Tomokazu Iwasaki, Shinji Takeoka, Hiroyuki Nishide^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We synthesized 3-dithiolthione-substituted polythiophene, poly[3-(1′,2′-dithiol-3′-thione-4′-yl)thiophene], by cyclization reaction of poly[3-bis(methoxycaronyl)methyl thiophene]. Its redox behavior and electronic states showed that the oxidation of the polythiophene followed the oxidation of the dithiolthione ring to the radical cation of the dithiolthione ring.

Original language	English
Pages (from-to)	1482-1483
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	11
DOIs	https://doi.org/10.1246/cl.2004.1482
Publication status	Published - 2004 Nov 5

ASJC Scopus subject areas

Chemistry(all)

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abstract = "We synthesized 3-dithiolthione-substituted polythiophene, poly[3-(1′,2′-dithiol-3′-thione-4′-yl)thiophene], by cyclization reaction of poly[3-bis(methoxycaronyl)methyl thiophene]. Its redox behavior and electronic states showed that the oxidation of the polythiophene followed the oxidation of the dithiolthione ring to the radical cation of the dithiolthione ring.",

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AU - Takemura, Ichiro

AU - Iwasaki, Tomokazu

AU - Takeoka, Shinji

AU - Nishide, Hiroyuki

PY - 2004/11/5

Y1 - 2004/11/5

N2 - We synthesized 3-dithiolthione-substituted polythiophene, poly[3-(1′,2′-dithiol-3′-thione-4′-yl)thiophene], by cyclization reaction of poly[3-bis(methoxycaronyl)methyl thiophene]. Its redox behavior and electronic states showed that the oxidation of the polythiophene followed the oxidation of the dithiolthione ring to the radical cation of the dithiolthione ring.

AB - We synthesized 3-dithiolthione-substituted polythiophene, poly[3-(1′,2′-dithiol-3′-thione-4′-yl)thiophene], by cyclization reaction of poly[3-bis(methoxycaronyl)methyl thiophene]. Its redox behavior and electronic states showed that the oxidation of the polythiophene followed the oxidation of the dithiolthione ring to the radical cation of the dithiolthione ring.

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JO - Chemistry Letters

JF - Chemistry Letters

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ER -

3-Dithiolthione-substituted polythiophene and its redox activities

Abstract

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