TY - JOUR
T1 - A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]+, cyclo-tetrakis(μ-1,4,7-trithiacyclononane-κ3S1,S 4,S7:κS1)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate
AU - Yamaguchi, Tadashi
AU - Yamazaki, Fumie
AU - Ito, Tasuku
PY - 2002/4
Y1 - 2002/4
N2 - (1,4,7-Trithiacyclononane) silver trifluoromethanesulfonate crystallizes in a tetrameric form from nitromethane, to give the title compound, [Ag4(C6H12S3)4](CF3 SO3)4·2CH3NO2. The complex cation consists of four [AgL]+ units (L is 1,4,7-trithiacyclononane), with four Ag-S-Ag bridges forming a cyclic tetramer. The almost planar Ag4S4 ring takes an octagonal form.
AB - (1,4,7-Trithiacyclononane) silver trifluoromethanesulfonate crystallizes in a tetrameric form from nitromethane, to give the title compound, [Ag4(C6H12S3)4](CF3 SO3)4·2CH3NO2. The complex cation consists of four [AgL]+ units (L is 1,4,7-trithiacyclononane), with four Ag-S-Ag bridges forming a cyclic tetramer. The almost planar Ag4S4 ring takes an octagonal form.
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U2 - 10.1107/S0108270102001075
DO - 10.1107/S0108270102001075
M3 - Article
C2 - 11932519
AN - SCOPUS:0036528904
SN - 0108-2701
VL - 58
SP - m213-m214
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 4
ER -