A [FeIII(Tp)(CN)3]- scorpionate-based complex as a building block for designing ion storage hosts (Tp: Hydrotrispyrazolylborate)

Juan Ramón Jiménez; Akira Sugahara; Masashi Okubo; Atsuo Yamada; Lise Marie Chamoreau; Laurent Lisnard; Rodrigue Lescouëzec

doi:10.1039/c8cc01374h

A [Fe^III(Tp)(CN)₃]^- scorpionate-based complex as a building block for designing ion storage hosts (Tp: Hydrotrispyrazolylborate)

Juan Ramón Jiménez, Akira Sugahara, Masashi Okubo, Atsuo Yamada, Lise Marie Chamoreau, Laurent Lisnard, Rodrigue Lescouëzec^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Using a scorpionate-based complex, [Fe^III(Tp)(CN)₃]^-, as a building block, a new cyanide-based molecular material [{Fe^III(Tp)(CN)₃}₂Ni^II(H₂O)₂]·4H₂O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.

Original language	English
Pages (from-to)	5189-5192
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	41
DOIs	https://doi.org/10.1039/c8cc01374h
Publication status	Published - 2018
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c8cc01374h

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title = "A [FeIII(Tp)(CN)3]- scorpionate-based complex as a building block for designing ion storage hosts (Tp: Hydrotrispyrazolylborate)",

abstract = "Using a scorpionate-based complex, [FeIII(Tp)(CN)3]-, as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.",

author = "Jim{\'e}nez, {Juan Ram{\'o}n} and Akira Sugahara and Masashi Okubo and Atsuo Yamada and Chamoreau, {Lise Marie} and Laurent Lisnard and Rodrigue Lescou{\"e}zec",

note = "Funding Information: This work was financially supported by the ANR-JST Strategic International Collaborative Research Program (SICORP), Molecular Technology, Molecular Materials for Magnesium Batteries (MoMa). X-ray absorption spectroscopy was conducted under the approval of the Photon Factory Program Advisory Committee (Proposal 2016G031). We thank B. Baptiste from IMPMC for the initial PXRD measurements. Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8cc01374h",

language = "English",

volume = "54",

pages = "5189--5192",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - A [FeIII(Tp)(CN)3]- scorpionate-based complex as a building block for designing ion storage hosts (Tp: Hydrotrispyrazolylborate)

AU - Jiménez, Juan Ramón

AU - Sugahara, Akira

AU - Okubo, Masashi

AU - Yamada, Atsuo

AU - Chamoreau, Lise Marie

AU - Lisnard, Laurent

AU - Lescouëzec, Rodrigue

N1 - Funding Information: This work was financially supported by the ANR-JST Strategic International Collaborative Research Program (SICORP), Molecular Technology, Molecular Materials for Magnesium Batteries (MoMa). X-ray absorption spectroscopy was conducted under the approval of the Photon Factory Program Advisory Committee (Proposal 2016G031). We thank B. Baptiste from IMPMC for the initial PXRD measurements. Publisher Copyright: © 2018 The Royal Society of Chemistry.

PY - 2018

Y1 - 2018

N2 - Using a scorpionate-based complex, [FeIII(Tp)(CN)3]-, as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.

AB - Using a scorpionate-based complex, [FeIII(Tp)(CN)3]-, as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.

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ER -

A [Fe^III(Tp)(CN)₃]^- scorpionate-based complex as a building block for designing ion storage hosts (Tp: Hydrotrispyrazolylborate)

Abstract

ASJC Scopus subject areas

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