A hybrid lithium oxalate-phosphinate salt

Andrew R. Shaffer; Nihal Deligonul; Daniel Alberto Scherson; John D. Protasiewicz

doi:10.1021/ic1018532

A hybrid lithium oxalate-phosphinate salt

Andrew R. Shaffer, Nihal Deligonul, Daniel Alberto Scherson, John D. Protasiewicz

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The novel organophosphorus-containing lithium salt Li(THF)[(C ₂O₄)B(O₂PPh₂)₂] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C₂O₄) B(O₂PPh₂)₂]₂·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.

Original language	English
Pages (from-to)	10756-10758
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	23
DOIs	https://doi.org/10.1021/ic1018532
Publication status	Published - 2010 Dec 6
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1021/ic1018532

Cite this

@article{c7c414c429ce4ca7825566a60cf0219e,

title = "A hybrid lithium oxalate-phosphinate salt",

abstract = "The novel organophosphorus-containing lithium salt Li(THF)[(C 2O4)B(O2PPh2)2] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C2O4) B(O2PPh2)2]2·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.",

author = "Shaffer, {Andrew R.} and Nihal Deligonul and Scherson, {Daniel Alberto} and Protasiewicz, {John D.}",

year = "2010",

month = dec,

day = "6",

doi = "10.1021/ic1018532",

language = "English",

volume = "49",

pages = "10756--10758",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - A hybrid lithium oxalate-phosphinate salt

AU - Shaffer, Andrew R.

AU - Deligonul, Nihal

AU - Scherson, Daniel Alberto

AU - Protasiewicz, John D.

PY - 2010/12/6

Y1 - 2010/12/6

N2 - The novel organophosphorus-containing lithium salt Li(THF)[(C 2O4)B(O2PPh2)2] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C2O4) B(O2PPh2)2]2·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.

AB - The novel organophosphorus-containing lithium salt Li(THF)[(C 2O4)B(O2PPh2)2] (1; THF = tetrahydrofuran) was synthesized and characterized using a variety of spectroscopic techniques. An X-ray structural analysis on crystals of 1 grown from THF reveals a dimeric structure [Li(THF)(C2O4) B(O2PPh2)2]2·THF, whereby the two units of 1 are bridged via P-O⋯Li interactions. Compound 1 displays high air and water stability and is also thermally robust, properties needed of electrolytes for their possible use as electrolytes and/or additives in lithium-ion battery applications.

UR - http://www.scopus.com/inward/record.url?scp=78650235685&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78650235685&partnerID=8YFLogxK

U2 - 10.1021/ic1018532

DO - 10.1021/ic1018532

M3 - Article

C2 - 21058666

AN - SCOPUS:78650235685

SN - 0020-1669

VL - 49

SP - 10756

EP - 10758

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 23

ER -

A hybrid lithium oxalate-phosphinate salt

Abstract

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this