A new method of synthesis of alkyl β-glycosides using sucrose as sugar donor

Kuniki Kino; Ryoko Satake; Takayuki Morimatsu; Shoko Kuratsu; Yu Shimizu; Masaru Sato; Kohtaro Kirimura

doi:10.1271/bbb.80097

A new method of synthesis of alkyl β-glycosides using sucrose as sugar donor

Kuniki Kino^*, Ryoko Satake, Takayuki Morimatsu, Shoko Kuratsu, Yu Shimizu, Masaru Sato, Kohtaro Kirimura

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Cellobiose phosphorylase from Clostridium thermocellum catalyzed the β-anomer-selective synthesis of alkyl glucosides from cellobiose. Synthesis of alkyl β-glucoside from inexpensive sucrose using cellobiose phosphorylase and sucrose phosphorylase from Pseudomonas saccharophilia was investigated. By combined use of these two phosphorylases, alkyl β-glucoside was anomer-selectively synthesized from sucrose and alkyl alcohol.

Original language	English
Pages (from-to)	2415-2417
Number of pages	3
Journal	Bioscience, Biotechnology and Biochemistry
Volume	72
Issue number	9
DOIs	https://doi.org/10.1271/bbb.80097
Publication status	Published - 2008

Keywords

Cellobiose phosphorylase
Sucrose phosphorylase
β-anomer-selective transglucosylation
β-glucoside

ASJC Scopus subject areas

Biotechnology
Analytical Chemistry
Biochemistry
Applied Microbiology and Biotechnology
Molecular Biology
Organic Chemistry

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10.1271/bbb.80097

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title = "A new method of synthesis of alkyl β-glycosides using sucrose as sugar donor",

abstract = "Cellobiose phosphorylase from Clostridium thermocellum catalyzed the β-anomer-selective synthesis of alkyl glucosides from cellobiose. Synthesis of alkyl β-glucoside from inexpensive sucrose using cellobiose phosphorylase and sucrose phosphorylase from Pseudomonas saccharophilia was investigated. By combined use of these two phosphorylases, alkyl β-glucoside was anomer-selectively synthesized from sucrose and alkyl alcohol.",

keywords = "Cellobiose phosphorylase, Sucrose phosphorylase, β-anomer-selective transglucosylation, β-glucoside",

author = "Kuniki Kino and Ryoko Satake and Takayuki Morimatsu and Shoko Kuratsu and Yu Shimizu and Masaru Sato and Kohtaro Kirimura",

note = "Funding Information: We are grateful to Dr. Motomitsu Kitaoka of the National Food Research Institute for providing recombinant CtCPase. This research was done at the {\textquoteleft}{\textquoteleft}Center for Practical Chemical Wisdom{\textquoteright}{\textquoteright} supported by the Global COE program of the Ministry of Education, Culture, Sports, Science and Technology of Japan.",

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doi = "10.1271/bbb.80097",

language = "English",

volume = "72",

pages = "2415--2417",

journal = "Bioscience, Biotechnology and Biochemistry",

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TY - JOUR

T1 - A new method of synthesis of alkyl β-glycosides using sucrose as sugar donor

AU - Kino, Kuniki

AU - Satake, Ryoko

AU - Morimatsu, Takayuki

AU - Kuratsu, Shoko

AU - Shimizu, Yu

AU - Sato, Masaru

AU - Kirimura, Kohtaro

N1 - Funding Information: We are grateful to Dr. Motomitsu Kitaoka of the National Food Research Institute for providing recombinant CtCPase. This research was done at the ‘‘Center for Practical Chemical Wisdom’’ supported by the Global COE program of the Ministry of Education, Culture, Sports, Science and Technology of Japan.

PY - 2008

Y1 - 2008

N2 - Cellobiose phosphorylase from Clostridium thermocellum catalyzed the β-anomer-selective synthesis of alkyl glucosides from cellobiose. Synthesis of alkyl β-glucoside from inexpensive sucrose using cellobiose phosphorylase and sucrose phosphorylase from Pseudomonas saccharophilia was investigated. By combined use of these two phosphorylases, alkyl β-glucoside was anomer-selectively synthesized from sucrose and alkyl alcohol.

AB - Cellobiose phosphorylase from Clostridium thermocellum catalyzed the β-anomer-selective synthesis of alkyl glucosides from cellobiose. Synthesis of alkyl β-glucoside from inexpensive sucrose using cellobiose phosphorylase and sucrose phosphorylase from Pseudomonas saccharophilia was investigated. By combined use of these two phosphorylases, alkyl β-glucoside was anomer-selectively synthesized from sucrose and alkyl alcohol.

KW - Cellobiose phosphorylase

KW - Sucrose phosphorylase

KW - β-anomer-selective transglucosylation

KW - β-glucoside

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DO - 10.1271/bbb.80097

M3 - Article

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AN - SCOPUS:52649110731

SN - 0916-8451

VL - 72

SP - 2415

EP - 2417

JO - Bioscience, Biotechnology and Biochemistry

JF - Bioscience, Biotechnology and Biochemistry

IS - 9

ER -

A new method of synthesis of alkyl β-glycosides using sucrose as sugar donor

Abstract

Keywords

ASJC Scopus subject areas

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