@article{bf7aa7044dc348c18a284830bd0f846a,
title = "A triplet biradical with double bidentate sites based on tert-butyl pyridyl nitroxide as a candidate for strong ferromagnetic couplers",
abstract = "We synthesised a new biradical, 34bpybNO, having two chelating radical sites and demonstrated its crystal structure and ground triplet nature. Frozen-solution magnetic measurement and electron spin resonance results revealed a strong intramolecular ferromagnetic coupling reaching 2J/kB = ∼+170 K, which is supported by density functional theory calculations.",
author = "Atsushi Okazawa and Yutaro Terakado and Takayuki Ishida and Norimichi Kojima",
note = "Funding Information: The authors thank Dr S. Takizawa and Prof. S. Murata (The University of Tokyo) for their support on UV-vis spectroscopy. This work was financially supported by JSPS KAKENHI Grant Numbers JP15K17841 and JP18K05057, and the research grant of Japan Association for Chemical Innovation. A part of this work was conducted at Advanced Characterization Nanotechnology Platform of the University of Tokyo, supported by {\textquoteleft}{\textquoteleft}Nanotechnology Platform{\textquoteright}{\textquoteright} of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan. Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.",
year = "2018",
doi = "10.1039/c8nj04180f",
language = "English",
volume = "42",
pages = "17874--17878",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "Royal Society of Chemistry",
number = "22",
}