Absolute chirality of the γ-polymorph of glycine: Correlation of the absolute structure with the optical rotation

Kazuhiko Ishikawa; Masahito Tanaka; Toshiya Suzuki; Akiko Sekine; Tsuneomi Kawasaki; Kenso Soai; Motoo Shiro; Meir Lahav; Toru Asahi

doi:10.1039/c2cc30549f

Absolute chirality of the γ-polymorph of glycine: Correlation of the absolute structure with the optical rotation

Kazuhiko Ishikawa, Masahito Tanaka, Toshiya Suzuki, Akiko Sekine, Tsuneomi Kawasaki, Kenso Soai, Motoo Shiro, Meir Lahav, Toru Asahi^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Crystal specimens of the γ-polymorph of achiral glycine which crystallize in space groups P3₁ and P3₂ as determined by the anomalous X-ray scattering method are shown to be laevorotatory and dextrorotatory, respectively, as determined by optical rotation of the crystals.

Original language	English
Pages (from-to)	6031-6033
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	48
DOIs	https://doi.org/10.1039/c2cc30549f
Publication status	Published - 2012 May 21

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Absolute chirality of the γ-polymorph of glycine: Correlation of the absolute structure with the optical rotation",

abstract = "Crystal specimens of the γ-polymorph of achiral glycine which crystallize in space groups P31 and P32 as determined by the anomalous X-ray scattering method are shown to be laevorotatory and dextrorotatory, respectively, as determined by optical rotation of the crystals.",

author = "Kazuhiko Ishikawa and Masahito Tanaka and Toshiya Suzuki and Akiko Sekine and Tsuneomi Kawasaki and Kenso Soai and Motoo Shiro and Meir Lahav and Toru Asahi",

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T1 - Absolute chirality of the γ-polymorph of glycine

T2 - Correlation of the absolute structure with the optical rotation

AU - Ishikawa, Kazuhiko

AU - Tanaka, Masahito

AU - Suzuki, Toshiya

AU - Sekine, Akiko

AU - Kawasaki, Tsuneomi

AU - Soai, Kenso

AU - Shiro, Motoo

AU - Lahav, Meir

AU - Asahi, Toru

PY - 2012/5/21

Y1 - 2012/5/21

N2 - Crystal specimens of the γ-polymorph of achiral glycine which crystallize in space groups P31 and P32 as determined by the anomalous X-ray scattering method are shown to be laevorotatory and dextrorotatory, respectively, as determined by optical rotation of the crystals.

AB - Crystal specimens of the γ-polymorph of achiral glycine which crystallize in space groups P31 and P32 as determined by the anomalous X-ray scattering method are shown to be laevorotatory and dextrorotatory, respectively, as determined by optical rotation of the crystals.

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U2 - 10.1039/c2cc30549f

DO - 10.1039/c2cc30549f

M3 - Article

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AN - SCOPUS:84861626940

SN - 1359-7345

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EP - 6033

JO - Chemical Communications

JF - Chemical Communications

IS - 48

ER -

Absolute chirality of the γ-polymorph of glycine: Correlation of the absolute structure with the optical rotation

Abstract

ASJC Scopus subject areas

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