TY - JOUR
T1 - Aging state analysis of cables insulated with ethylene propylene diene rubber exposed to simulated severe accident conditions
AU - Minakawa, Takefumi
AU - Ikeda, Masaaki
AU - Hirai, Naoshi
AU - Ohki, Yoshimichi
N1 - Publisher Copyright:
© 2019 The Institute of Electrical Engineers of Japan.
PY - 2019
Y1 - 2019
N2 - Several cables in safety-related systems in nuclear power plants (NPPs) are required to perform their safety functions in severe accident conditions even after they experience inservice aging. For such cables, the behavior of their insulation under the accidents is a matter of concern. In this research, after cables insulated with ethylene propylene diene rubber (EPDM) were preconditioned by exposing them to concurrent heat and radiation to simulate aging that would be incurred in their service life in normal operating condition of NPPs, they were exposed to radiation and high temperature steam that simulate harsh accident conditions postulated inside the primary containment vessel. The changes in chemical structures and thermal and mechanical properties were analyzed by Fourier transform infrared spectroscopy, thermogravimetry, and indentation hardness measurements. As a result, it has been confirmed that the pre-aging and radiation exposure induce chain scission by oxidation and cross-linking, whereas the steam exposure causes bleedout of additives compounded in EPDM.
AB - Several cables in safety-related systems in nuclear power plants (NPPs) are required to perform their safety functions in severe accident conditions even after they experience inservice aging. For such cables, the behavior of their insulation under the accidents is a matter of concern. In this research, after cables insulated with ethylene propylene diene rubber (EPDM) were preconditioned by exposing them to concurrent heat and radiation to simulate aging that would be incurred in their service life in normal operating condition of NPPs, they were exposed to radiation and high temperature steam that simulate harsh accident conditions postulated inside the primary containment vessel. The changes in chemical structures and thermal and mechanical properties were analyzed by Fourier transform infrared spectroscopy, thermogravimetry, and indentation hardness measurements. As a result, it has been confirmed that the pre-aging and radiation exposure induce chain scission by oxidation and cross-linking, whereas the steam exposure causes bleedout of additives compounded in EPDM.
KW - Ethylene propylene diene rubber
KW - Nuclear power plant
KW - Safety-related cable
KW - Severe accident
KW - Steam exposure
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U2 - 10.1541/ieejfms.139.380
DO - 10.1541/ieejfms.139.380
M3 - Article
AN - SCOPUS:85071884181
SN - 0385-4205
VL - 139
SP - 380
EP - 386
JO - IEEJ Transactions on Fundamentals and Materials
JF - IEEJ Transactions on Fundamentals and Materials
IS - 9
ER -