TY - JOUR
T1 - Allylic carbonates. Efficient allylating agents of carbonucleophiles in palladium-catalyzed reactions under neutral conditions
AU - Tsuji, Jiro
AU - Shimizu, Isao
AU - Minami, Ichiro
AU - Ohashi, Yukihiro
AU - Sugiura, Teruo
AU - Takahashi, Kazuhiko
PY - 1985
Y1 - 1985
N2 - Allylation of β-keto esters or malonates was carried out in good yields under neutral conditions by using allylic carbonates in the presence of palladium-phosphine catalyst. Although simple ketones, esters, nitriles, and sulfones hardly react with allylic carbonates, α-alkenyl or α-aryl ketones, esters, nitriles, and sulfones were also allylated by using palladium-bis(diphenylphosphino)ethane catalyst under neutral conditions.
AB - Allylation of β-keto esters or malonates was carried out in good yields under neutral conditions by using allylic carbonates in the presence of palladium-phosphine catalyst. Although simple ketones, esters, nitriles, and sulfones hardly react with allylic carbonates, α-alkenyl or α-aryl ketones, esters, nitriles, and sulfones were also allylated by using palladium-bis(diphenylphosphino)ethane catalyst under neutral conditions.
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M3 - Article
AN - SCOPUS:33845379388
SN - 0022-3263
VL - 50
SP - 1523
EP - 1529
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 9
ER -