An alluaudite Na2 + 2xFe2 - X(SO4)3(x = 0.2) derivative phase as insertion host for lithium battery

Jun Ming; Prabeer Barpanda; Shin Ichi Nishimura; Masashi Okubo; Atsuo Yamada

doi:10.1016/j.elecom.2014.11.009

An alluaudite Na_{2 + 2x}Fe_{2 - X}(SO₄)₃(x = 0.2) derivative phase as insertion host for lithium battery

Jun Ming, Prabeer Barpanda, Shin Ichi Nishimura, Masashi Okubo, Atsuo Yamada^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

A new desodiated derivative compound, Na_0.89Fe_1.8(SO₄)₃, was prepared by the chemical oxidation of alluaudite Na_2.4Fe_1.8(SO₄)₃ phase using NOBF₄ as oxidant. The structure and valency of Fe were characterized by X-ray diffraction (XRD) and ⁵⁷Fe Mössbauer spectroscopy. Intercalation behavior of lithium ions in the structure of Na_0.89Fe_1.8(SO₄)₃ was gauged by electrochemical analyses and ex-situ X-ray diffraction. A high capacity of 110 mAh g^{- 1} at 0.1 C was obtained with a good rate kinetics within a range of 0.1-10 C(1 C = 118 mAh g^{- 1}) involving a high Fe^{3 +}/Fe^{2 +} redox potential of 3.75 V (vs. Li/Li⁺). These results confirmed that the Na_{2.4- δ}Fe_1.8(SO₄)₃ framework was stable even after oxidation and forms a new competitive cathode for the reversible intercalation of lithium ions.

Original language	English
Pages (from-to)	19-22
Number of pages	4
Journal	Electrochemistry Communications
Volume	51
DOIs	https://doi.org/10.1016/j.elecom.2014.11.009
Publication status	Published - 2015 Feb
Externally published	Yes

Keywords

Alluaudite
Cathode
Lithium batteries
Oxidation
Sodium batteries

ASJC Scopus subject areas

Electrochemistry

Access to Document

10.1016/j.elecom.2014.11.009

Cite this

@article{274fdea50f39426489c7f6a767ad2510,

title = "An alluaudite Na2 + 2xFe2 - X(SO4)3(x = 0.2) derivative phase as insertion host for lithium battery",

abstract = "A new desodiated derivative compound, Na0.89Fe1.8(SO4)3, was prepared by the chemical oxidation of alluaudite Na2.4Fe1.8(SO4)3 phase using NOBF4 as oxidant. The structure and valency of Fe were characterized by X-ray diffraction (XRD) and 57Fe M{\"o}ssbauer spectroscopy. Intercalation behavior of lithium ions in the structure of Na0.89Fe1.8(SO4)3 was gauged by electrochemical analyses and ex-situ X-ray diffraction. A high capacity of 110 mAh g- 1 at 0.1 C was obtained with a good rate kinetics within a range of 0.1-10 C(1 C = 118 mAh g- 1) involving a high Fe3 +/Fe2 + redox potential of 3.75 V (vs. Li/Li+). These results confirmed that the Na2.4- δFe1.8(SO4)3 framework was stable even after oxidation and forms a new competitive cathode for the reversible intercalation of lithium ions.",

keywords = "Alluaudite, Cathode, Lithium batteries, Oxidation, Sodium batteries",

author = "Jun Ming and Prabeer Barpanda and Nishimura, {Shin Ichi} and Masashi Okubo and Atsuo Yamada",

note = "Funding Information: We acknowledge the financial support from the Ministry of Education, Culture, Sports, Science and Technology , Japan (MEXT) under the {\textquoteleft}Elemental Strategy Initiative for Catalysts & Batteries{\textquoteright} (ESICB) project. Publisher Copyright: {\textcopyright} 2014 Elsevier B.V. All rights reserved.",

year = "2015",

month = feb,

doi = "10.1016/j.elecom.2014.11.009",

language = "English",

volume = "51",

pages = "19--22",

journal = "Electrochemistry Communications",

issn = "1388-2481",

publisher = "Elsevier Inc.",

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TY - JOUR

T1 - An alluaudite Na2 + 2xFe2 - X(SO4)3(x = 0.2) derivative phase as insertion host for lithium battery

AU - Ming, Jun

AU - Barpanda, Prabeer

AU - Nishimura, Shin Ichi

AU - Okubo, Masashi

AU - Yamada, Atsuo

N1 - Funding Information: We acknowledge the financial support from the Ministry of Education, Culture, Sports, Science and Technology , Japan (MEXT) under the ‘Elemental Strategy Initiative for Catalysts & Batteries’ (ESICB) project. Publisher Copyright: © 2014 Elsevier B.V. All rights reserved.

PY - 2015/2

Y1 - 2015/2

N2 - A new desodiated derivative compound, Na0.89Fe1.8(SO4)3, was prepared by the chemical oxidation of alluaudite Na2.4Fe1.8(SO4)3 phase using NOBF4 as oxidant. The structure and valency of Fe were characterized by X-ray diffraction (XRD) and 57Fe Mössbauer spectroscopy. Intercalation behavior of lithium ions in the structure of Na0.89Fe1.8(SO4)3 was gauged by electrochemical analyses and ex-situ X-ray diffraction. A high capacity of 110 mAh g- 1 at 0.1 C was obtained with a good rate kinetics within a range of 0.1-10 C(1 C = 118 mAh g- 1) involving a high Fe3 +/Fe2 + redox potential of 3.75 V (vs. Li/Li+). These results confirmed that the Na2.4- δFe1.8(SO4)3 framework was stable even after oxidation and forms a new competitive cathode for the reversible intercalation of lithium ions.

AB - A new desodiated derivative compound, Na0.89Fe1.8(SO4)3, was prepared by the chemical oxidation of alluaudite Na2.4Fe1.8(SO4)3 phase using NOBF4 as oxidant. The structure and valency of Fe were characterized by X-ray diffraction (XRD) and 57Fe Mössbauer spectroscopy. Intercalation behavior of lithium ions in the structure of Na0.89Fe1.8(SO4)3 was gauged by electrochemical analyses and ex-situ X-ray diffraction. A high capacity of 110 mAh g- 1 at 0.1 C was obtained with a good rate kinetics within a range of 0.1-10 C(1 C = 118 mAh g- 1) involving a high Fe3 +/Fe2 + redox potential of 3.75 V (vs. Li/Li+). These results confirmed that the Na2.4- δFe1.8(SO4)3 framework was stable even after oxidation and forms a new competitive cathode for the reversible intercalation of lithium ions.

KW - Alluaudite

KW - Cathode

KW - Lithium batteries

KW - Oxidation

KW - Sodium batteries

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