An enantioselective Baylis-Hillman reaction catalyzed by chiral phosphines under atmospheric pressure

Tadakatsu Hayase; Takanori Shibata; Kenso Soai; Yasuo Wakatsuki

doi:10.1039/a802594k

An enantioselective Baylis-Hillman reaction catalyzed by chiral phosphines under atmospheric pressure

Tadakatsu Hayase, Takanori Shibata, Kenso Soai^*, Yasuo Wakatsuki

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

110 Citations (Scopus)

Abstract

2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl (BINAP) catalyzes the enantioselective Baylis-Hillman reaction between pyrimidine- 5-carbaldehydes and acrylates to provide chiral α-methylene ß-hydroxy esters in up to 44% ee under atmospheric pressure.

Original language	English
Pages (from-to)	1271-1272
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/a802594k
Publication status	Published - 1998 Jun 21
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "An enantioselective Baylis-Hillman reaction catalyzed by chiral phosphines under atmospheric pressure",

abstract = "2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl (BINAP) catalyzes the enantioselective Baylis-Hillman reaction between pyrimidine- 5-carbaldehydes and acrylates to provide chiral α-methylene {\ss}-hydroxy esters in up to 44% ee under atmospheric pressure.",

author = "Tadakatsu Hayase and Takanori Shibata and Kenso Soai and Yasuo Wakatsuki",

year = "1998",

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T1 - An enantioselective Baylis-Hillman reaction catalyzed by chiral phosphines under atmospheric pressure

AU - Hayase, Tadakatsu

AU - Shibata, Takanori

AU - Soai, Kenso

AU - Wakatsuki, Yasuo

PY - 1998/6/21

Y1 - 1998/6/21

N2 - 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl (BINAP) catalyzes the enantioselective Baylis-Hillman reaction between pyrimidine- 5-carbaldehydes and acrylates to provide chiral α-methylene ß-hydroxy esters in up to 44% ee under atmospheric pressure.

AB - 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl (BINAP) catalyzes the enantioselective Baylis-Hillman reaction between pyrimidine- 5-carbaldehydes and acrylates to provide chiral α-methylene ß-hydroxy esters in up to 44% ee under atmospheric pressure.

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DO - 10.1039/a802594k

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JO - Chemical Communications

JF - Chemical Communications

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ER -

An enantioselective Baylis-Hillman reaction catalyzed by chiral phosphines under atmospheric pressure

Abstract

ASJC Scopus subject areas

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