An inorganic-organic hybrid possessing a two-dimensional Ti-O network and surface ethoxy groups prepared via a reaction of titanium oxychloride with lithium ethoxide

Natsuki Watanabe; Yoshitaka Kamochi; Seiichi Tahara; Nobuhiro Kumada; Yoshiyuki Sugahara

doi:10.1246/cl.2009.244

An inorganic-organic hybrid possessing a two-dimensional Ti-O network and surface ethoxy groups prepared via a reaction of titanium oxychloride with lithium ethoxide

Natsuki Watanabe, Yoshitaka Kamochi, Seiichi Tahara, Nobuhiro Kumada, Yoshiyuki Sugahara^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A new layered inorganic-organic hybrid possessing a Ti-O network has been prepared by a reaction between titanium oxychloride (TiOCl) and lithium ethoxide (LiOEt) at 120 °C for 7 days. The XRD analysis indicates that the interlayer distance of TiOCl increases from 0.80 to 1.19nm, and the solid-state ¹³CNMR spectroscopy and elemental analysis show partial substitution of ethoxy groups for chlorine atoms.

Original language	English
Pages (from-to)	244-245
Number of pages	2
Journal	Chemistry Letters
Volume	38
Issue number	3
DOIs	https://doi.org/10.1246/cl.2009.244
Publication status	Published - 2009

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2009.244

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abstract = "A new layered inorganic-organic hybrid possessing a Ti-O network has been prepared by a reaction between titanium oxychloride (TiOCl) and lithium ethoxide (LiOEt) at 120 °C for 7 days. The XRD analysis indicates that the interlayer distance of TiOCl increases from 0.80 to 1.19nm, and the solid-state 13CNMR spectroscopy and elemental analysis show partial substitution of ethoxy groups for chlorine atoms.",

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AU - Watanabe, Natsuki

AU - Kamochi, Yoshitaka

AU - Tahara, Seiichi

AU - Kumada, Nobuhiro

AU - Sugahara, Yoshiyuki

PY - 2009

Y1 - 2009

N2 - A new layered inorganic-organic hybrid possessing a Ti-O network has been prepared by a reaction between titanium oxychloride (TiOCl) and lithium ethoxide (LiOEt) at 120 °C for 7 days. The XRD analysis indicates that the interlayer distance of TiOCl increases from 0.80 to 1.19nm, and the solid-state 13CNMR spectroscopy and elemental analysis show partial substitution of ethoxy groups for chlorine atoms.

AB - A new layered inorganic-organic hybrid possessing a Ti-O network has been prepared by a reaction between titanium oxychloride (TiOCl) and lithium ethoxide (LiOEt) at 120 °C for 7 days. The XRD analysis indicates that the interlayer distance of TiOCl increases from 0.80 to 1.19nm, and the solid-state 13CNMR spectroscopy and elemental analysis show partial substitution of ethoxy groups for chlorine atoms.

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An inorganic-organic hybrid possessing a two-dimensional Ti-O network and surface ethoxy groups prepared via a reaction of titanium oxychloride with lithium ethoxide

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