Application of Solid Polymer Electrolyte to Lithium/Polypyrrole Secondary Battery System

Tetsuya Osaka; Toshiyuki Mommo; Ken Nishimura; Satoko Kakuda; Takayuki Ishii

doi:10.1149/1.2055048

Application of Solid Polymer Electrolyte to Lithium/Polypyrrole Secondary Battery System

Tetsuya Osaka, Toshiyuki Mommo, Ken Nishimura, Satoko Kakuda, Takayuki Ishii

Research output: Contribution to journal › Article › peer-review

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Abstract

An all solid-state lithium/polypyrrole (PPy) battery using polyethylene oxide (PEO)-LiClO₄ as a solid polymer electrolyte was assembled, and the effects of the morphology of the PPy film and the concentration of LiC10₄ on battery performance were investigated. Optimum conditions for the redox properties of PPy films in PEO-LiClO₄ at 80°C were obtained with an LiC10₄ concentration of n = 8 ~ 20 (n=[EO]/[Li]) when using rough PPy film. A Li/PPy battery using PEO-LiClO₄ with optimized conditions exhibited high coulombic efficiency, above 90% at 0.1 mA cm^-2 at 80°C. Cyclability of 1400 cycles with high coulombic efficiency was attained.

Original language	English
Pages (from-to)	1994-1998
Number of pages	5
Journal	Journal of the Electrochemical Society
Volume	141
Issue number	8
DOIs	https://doi.org/10.1149/1.2055048
Publication status	Published - 1994 Aug

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

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abstract = "An all solid-state lithium/polypyrrole (PPy) battery using polyethylene oxide (PEO)-LiClO4 as a solid polymer electrolyte was assembled, and the effects of the morphology of the PPy film and the concentration of LiC104 on battery performance were investigated. Optimum conditions for the redox properties of PPy films in PEO-LiClO4 at 80°C were obtained with an LiC104 concentration of n = 8 ~ 20 (n=[EO]/[Li]) when using rough PPy film. A Li/PPy battery using PEO-LiClO4 with optimized conditions exhibited high coulombic efficiency, above 90% at 0.1 mA cm-2 at 80°C. Cyclability of 1400 cycles with high coulombic efficiency was attained.",

author = "Tetsuya Osaka and Toshiyuki Mommo and Ken Nishimura and Satoko Kakuda and Takayuki Ishii",

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AU - Osaka, Tetsuya

AU - Mommo, Toshiyuki

AU - Nishimura, Ken

AU - Kakuda, Satoko

AU - Ishii, Takayuki

PY - 1994/8

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AB - An all solid-state lithium/polypyrrole (PPy) battery using polyethylene oxide (PEO)-LiClO4 as a solid polymer electrolyte was assembled, and the effects of the morphology of the PPy film and the concentration of LiC104 on battery performance were investigated. Optimum conditions for the redox properties of PPy films in PEO-LiClO4 at 80°C were obtained with an LiC104 concentration of n = 8 ~ 20 (n=[EO]/[Li]) when using rough PPy film. A Li/PPy battery using PEO-LiClO4 with optimized conditions exhibited high coulombic efficiency, above 90% at 0.1 mA cm-2 at 80°C. Cyclability of 1400 cycles with high coulombic efficiency was attained.

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Application of Solid Polymer Electrolyte to Lithium/Polypyrrole Secondary Battery System

Abstract

ASJC Scopus subject areas

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