Asymmetric induction by helical hydrocarbons: [6]-and [5]helicenes

Itaru Sato; Ryutaro Yamashima; Kousuke Kadowaki; Jun Yamamoto; Takanori Shibata; Kenso Soai

doi:10.1002/1521-3773(20010316)40:6<1096::AID-ANIE10960>3.0.CO;2-K

Asymmetric induction by helical hydrocarbons: [6]-and [5]helicenes

Itaru Sato, Ryutaro Yamashima, Kousuke Kadowaki, Jun Yamamoto, Takanori Shibata, Kenso Soai

Research output: Contribution to journal › Article › peer-review

187 Citations (Scopus)

Abstract

Helicenes without any heteroatoms have been shown for the first time to act as chiral inducers in the highly enantioselective addition of diisopropylzinc to an aldehyde (see scheme).

Original language	English
Pages (from-to)	1096-1098
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	6
DOIs	https://doi.org/10.1002/1521-3773(20010316)40:6<1096::AID-ANIE10960>3.0.CO;2-K
Publication status	Published - 2001 Mar 14
Externally published	Yes

Keywords

Asymmetric amplification
Asymmetric catalysis
Autocatalysis
Chirality
Helical structures

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/1521-3773(20010316)40:6<1096::AID-ANIE10960>3.0.CO;2-K

Cite this

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title = "Asymmetric induction by helical hydrocarbons: [6]-and [5]helicenes",

abstract = "Helicenes without any heteroatoms have been shown for the first time to act as chiral inducers in the highly enantioselective addition of diisopropylzinc to an aldehyde (see scheme).",

keywords = "Asymmetric amplification, Asymmetric catalysis, Autocatalysis, Chirality, Helical structures",

author = "Itaru Sato and Ryutaro Yamashima and Kousuke Kadowaki and Jun Yamamoto and Takanori Shibata and Kenso Soai",

year = "2001",

month = mar,

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doi = "10.1002/1521-3773(20010316)40:6<1096::AID-ANIE10960>3.0.CO;2-K",

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T1 - Asymmetric induction by helical hydrocarbons

T2 - [6]-and [5]helicenes

AU - Sato, Itaru

AU - Yamashima, Ryutaro

AU - Kadowaki, Kousuke

AU - Yamamoto, Jun

AU - Shibata, Takanori

AU - Soai, Kenso

PY - 2001/3/14

Y1 - 2001/3/14

N2 - Helicenes without any heteroatoms have been shown for the first time to act as chiral inducers in the highly enantioselective addition of diisopropylzinc to an aldehyde (see scheme).

AB - Helicenes without any heteroatoms have been shown for the first time to act as chiral inducers in the highly enantioselective addition of diisopropylzinc to an aldehyde (see scheme).

KW - Asymmetric amplification

KW - Asymmetric catalysis

KW - Autocatalysis

KW - Chirality

KW - Helical structures

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U2 - 10.1002/1521-3773(20010316)40:6<1096::AID-ANIE10960>3.0.CO;2-K

DO - 10.1002/1521-3773(20010316)40:6<1096::AID-ANIE10960>3.0.CO;2-K

M3 - Article

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VL - 40

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 6

ER -

Asymmetric induction by helical hydrocarbons: [6]-and [5]helicenes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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