@article{7c192472e23b415082fa426182514539,
title = "Asymmetric synthesis of N-(diphenylphosphinyl)-ferrocenylamine by the enantioselective alkylation of ferrocenylimine",
abstract = "Optically active N-(diphenylphosphinyl)ferrocenylamines with good to high e.e.'s were obtained by the enantioselective addition of dialkylzincs to ferrocenyl-diphenylphosphinylimine in the presence of chiral β-aminoalcohols. The subsequent hydrolysis afforded a chiral ferrocenylamine without racemization.",
author = "Tadakatsu Hayase and Yukikazu Inoue and Takanori Shibata and Kenso Soai",
note = "Funding Information: As described, the present method directly provides optically active protected ferrocenylalkylamines. 9 References 1. T. Hayashi and M. Kumada, Acc. Chem. Res., 1982, 15, 395; M. Sawamura and Y. Ito, Chent Rev., 1992, 92, 857; A. Togni, C. Breutel, A. Schnyder, F. Spindler, H. Landert and A. Tijani, J. Am. Chem. Soc., 1994, 116, 4062. 2. Y. Matsumoto, A. Ohno, S. Lu, T. Hayashi, N. Oguni and M. Hayashi, Tetrahedron: Asymmetry, 1993, 4, 1763; L. Schwink and P. Knochel, Tetrahedron Lett., 1996, 37, 25. 3. K. Soai, T. Hayase and K. Takai, Tetrahedron: Asymmetry, 1995, 6, 637; K. Soai, T. Hayase, K. Takai and T. Sugiyama, J. Org. Chem., 1994, 59, 7908; M. Watanabe, Synlett, 1995, 1050. 4. D.M. David, L. A. P. Kane-Maguire and S. G. Pyne, J. Chent Soc., Chem. Commun., 1990, 888. 5. D. Enders, R. Lochtman and G. Raabe, Synlett, 1996, 126. 6. K. Soai, T. Hatanaka and T. Miyazawa, J. Chem. Soc., Chem. Commun., 1992, 1097. 7. K. Tomioka, I. Inoue, M. Shindo and K. Koga, Tetrahedron Left., 1991, 32, 3095; S. Itsuno, H. Yanaka, C. Hachisuka and K. Ito, J. Chent Soc., Perkin Trans. 1, 1991, 3095; A. R. Katritzky and P. A. Harris, Tetrahedron: Asymmetry, 1992, 3, 437. 8. cf. W. B. Jennings and J. Lovely, Tetrahedron, 1991, 47, 5561 9. This work was financially supported by The New Energy and Technology Development Organization and by a Grant-in-Aid for Scientific Research from The Ministry of Education, Science, Sports and Culture.",
year = "1996",
month = sep,
doi = "10.1016/0957-4166(96)00319-9",
language = "English",
volume = "7",
pages = "2509--2510",
journal = "Tetrahedron Asymmetry",
issn = "0957-4166",
publisher = "Elsevier Limited",
number = "9",
}