TY - JOUR
T1 - Benzene-Oxygen Reaction Over Alkaline Earth Metal Oxide Catalysts.
AU - Matsukata, Masahiko
AU - Okanari, Eiji
AU - Kikuchi, Eiichi
AU - Morita, Yoshiro
PY - 1991
Y1 - 1991
N2 - The benzene-oxygen reaction catalyzed by alkaline earth metal oxides was investigated in the temperature range 773-1,073K to understand the catalytic function of these oxides for hydrocarbon gasification. In the initial stage of reaction, CO, CO2, H2O, and biphenyl were concurrently produced. The consumption of CO and H2O by the water-gas shift reaction subsequently occurred to give CO2and H2. CO oxidation with O2hardly occurred in the course of the benzene-oxygen reaction because benzene was preferentially adsorbed on the MgO catalyst. These reaction sequences were compared with those in the benzene-oxygen reaction catalyzed by metallic nickel.
AB - The benzene-oxygen reaction catalyzed by alkaline earth metal oxides was investigated in the temperature range 773-1,073K to understand the catalytic function of these oxides for hydrocarbon gasification. In the initial stage of reaction, CO, CO2, H2O, and biphenyl were concurrently produced. The consumption of CO and H2O by the water-gas shift reaction subsequently occurred to give CO2and H2. CO oxidation with O2hardly occurred in the course of the benzene-oxygen reaction because benzene was preferentially adsorbed on the MgO catalyst. These reaction sequences were compared with those in the benzene-oxygen reaction catalyzed by metallic nickel.
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U2 - 10.1627/jpi1958.34.36
DO - 10.1627/jpi1958.34.36
M3 - Article
AN - SCOPUS:85008036027
SN - 0582-4664
VL - 34
SP - 36
EP - 43
JO - Journal of The Japan Petroleum Institute
JF - Journal of The Japan Petroleum Institute
IS - 1
ER -