Biomimetic systems involving sequential redox reactions in glycolysis-the sulfur effect

Narihito Ogawa; Sei Furukawa; Yuya Kosugi; Takayuki Takazawa; Nobuhiro Kanomata

doi:10.1039/d0cc05185c

Biomimetic systems involving sequential redox reactions in glycolysis-the sulfur effect

Narihito Ogawa^*, Sei Furukawa, Yuya Kosugi, Takayuki Takazawa, Nobuhiro Kanomata

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Magnesium hemithioacetates were used as model cysteine compounds to mimic natural hemithioacetals, and their biomimetic oxidation reactions using a model NAD+ compound were investigated. Cyclic hemithioacetate was found to be the best substrate for the reaction with the model NAD+ compound, which gave the corresponding NADH analog in excellent yield. This journal is

Original language	English
Pages (from-to)	12917-12920
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	85
DOIs	https://doi.org/10.1039/d0cc05185c
Publication status	Published - 2020 Nov 4

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Ogawa, Narihito

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AU - Kosugi, Yuya

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AU - Kanomata, Nobuhiro

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/11/4

Y1 - 2020/11/4

N2 - Magnesium hemithioacetates were used as model cysteine compounds to mimic natural hemithioacetals, and their biomimetic oxidation reactions using a model NAD+ compound were investigated. Cyclic hemithioacetate was found to be the best substrate for the reaction with the model NAD+ compound, which gave the corresponding NADH analog in excellent yield. This journal is

AB - Magnesium hemithioacetates were used as model cysteine compounds to mimic natural hemithioacetals, and their biomimetic oxidation reactions using a model NAD+ compound were investigated. Cyclic hemithioacetate was found to be the best substrate for the reaction with the model NAD+ compound, which gave the corresponding NADH analog in excellent yield. This journal is

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Biomimetic systems involving sequential redox reactions in glycolysis-the sulfur effect

Abstract

ASJC Scopus subject areas

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