C-H alkenylation of azoles with enols and esters by nickel catalysis

Lingkui Meng; Yuko Kamada; Kei Muto; Junichiro Yamaguchi; Kenichiro Itami

doi:10.1002/anie.201304492

C-H alkenylation of azoles with enols and esters by nickel catalysis

Lingkui Meng, Yuko Kamada, Kei Muto, Junichiro Yamaguchi, Kenichiro Itami

Research output: Contribution to journal › Article › peer-review

135 Citations (Scopus)

Abstract

Rather u(Ni)que: Two new C-H alkenylation reactions, that is C-H/Cï£¿O alkenylation and decarbonylative C-H alkenylation, of azoles are uniquely catalyzed by Ni/dcype. These azole alkenylation reactions are successfully applied to the convergent formal synthesis of siphonazoleB.

Original language	English
Pages (from-to)	10048-10051
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	38
DOIs	https://doi.org/10.1002/anie.201304492
Publication status	Published - 2013 Sept 16
Externally published	Yes

Keywords

C-H activation
alkenes
heterocycles
natural products
nickel

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201304492

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AU - Kamada, Yuko

AU - Muto, Kei

AU - Yamaguchi, Junichiro

AU - Itami, Kenichiro

PY - 2013/9/16

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KW - C-H activation

KW - alkenes

KW - heterocycles

KW - natural products

KW - nickel

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C-H alkenylation of azoles with enols and esters by nickel catalysis

Abstract

Keywords

ASJC Scopus subject areas

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