Carbonylative and hydrosilylative carbocyclization of 1,5-diynes for the synthesis of cyclic dienones

Takanori Shibata; Naohisa Nakagawa; Yasunori Ueno; Kohei Endo

doi:10.1021/om7012277

Carbonylative and hydrosilylative carbocyclization of 1,5-diynes for the synthesis of cyclic dienones

Takanori Shibata^*, Naohisa Nakagawa, Yasunori Ueno, Kohei Endo

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A rhodium complex, [Rh(acac)(CO)₂], has been identified to catalyze the cyclization of various 1,5-diynes with hydrosilanes under an atmospheric pressure of carbon monoxide at room temperature. The cyclization of 1,5-diynes proceeds along with hydrosilylation and carbonylation to give derivatives of 2,5-dialkylidenecyclopentanone.

Original language	English
Pages (from-to)	1342-1344
Number of pages	3
Journal	Organometallics
Volume	27
Issue number	6
DOIs	https://doi.org/10.1021/om7012277
Publication status	Published - 2008 Mar 24

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om7012277

Cite this

@article{108328db7ee94dd4b09235066f290799,

title = "Carbonylative and hydrosilylative carbocyclization of 1,5-diynes for the synthesis of cyclic dienones",

abstract = "A rhodium complex, [Rh(acac)(CO)2], has been identified to catalyze the cyclization of various 1,5-diynes with hydrosilanes under an atmospheric pressure of carbon monoxide at room temperature. The cyclization of 1,5-diynes proceeds along with hydrosilylation and carbonylation to give derivatives of 2,5-dialkylidenecyclopentanone.",

author = "Takanori Shibata and Naohisa Nakagawa and Yasunori Ueno and Kohei Endo",

year = "2008",

month = mar,

day = "24",

doi = "10.1021/om7012277",

language = "English",

volume = "27",

pages = "1342--1344",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Carbonylative and hydrosilylative carbocyclization of 1,5-diynes for the synthesis of cyclic dienones

AU - Shibata, Takanori

AU - Nakagawa, Naohisa

AU - Ueno, Yasunori

AU - Endo, Kohei

PY - 2008/3/24

Y1 - 2008/3/24

N2 - A rhodium complex, [Rh(acac)(CO)2], has been identified to catalyze the cyclization of various 1,5-diynes with hydrosilanes under an atmospheric pressure of carbon monoxide at room temperature. The cyclization of 1,5-diynes proceeds along with hydrosilylation and carbonylation to give derivatives of 2,5-dialkylidenecyclopentanone.

AB - A rhodium complex, [Rh(acac)(CO)2], has been identified to catalyze the cyclization of various 1,5-diynes with hydrosilanes under an atmospheric pressure of carbon monoxide at room temperature. The cyclization of 1,5-diynes proceeds along with hydrosilylation and carbonylation to give derivatives of 2,5-dialkylidenecyclopentanone.

UR - http://www.scopus.com/inward/record.url?scp=41749088056&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=41749088056&partnerID=8YFLogxK

U2 - 10.1021/om7012277

DO - 10.1021/om7012277

M3 - Article

AN - SCOPUS:41749088056

SN - 0276-7333

VL - 27

SP - 1342

EP - 1344

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Carbonylative and hydrosilylative carbocyclization of 1,5-diynes for the synthesis of cyclic dienones

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this