Cationic Au(I)-catalyzed cycloisomerization of aromatic enynes for the synthesis of substituted naphthalenes

Takanori Shibata; Yasunori Ueno; Kazumasa Kanda

doi:10.1055/s-2006-926261

Cationic Au(I)-catalyzed cycloisomerization of aromatic enynes for the synthesis of substituted naphthalenes

Takanori Shibata^*, Yasunori Ueno, Kazumasa Kanda

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

A cationic Au(I) complex catalyzed the cycloisomerization of aromatic enynes that possess a substituent on their alkyne terminus. Cyclization of the 6-endo-dig type proceeded dominantly to give 1,3-di- and 1,2,3-trisubstituted naphthalenes.

Original language	English
Pages (from-to)	411-414
Number of pages	4
Journal	Synlett
Issue number	3
DOIs	https://doi.org/10.1055/s-2006-926261
Publication status	Published - 2006 Feb 15

Keywords

Catalysis
Cycloisomerization
Enynes
Gold
Indenes
Naphthalenes

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-2006-926261

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title = "Cationic Au(I)-catalyzed cycloisomerization of aromatic enynes for the synthesis of substituted naphthalenes",

abstract = "A cationic Au(I) complex catalyzed the cycloisomerization of aromatic enynes that possess a substituent on their alkyne terminus. Cyclization of the 6-endo-dig type proceeded dominantly to give 1,3-di- and 1,2,3-trisubstituted naphthalenes.",

keywords = "Catalysis, Cycloisomerization, Enynes, Gold, Indenes, Naphthalenes",

author = "Takanori Shibata and Yasunori Ueno and Kazumasa Kanda",

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AU - Shibata, Takanori

AU - Ueno, Yasunori

AU - Kanda, Kazumasa

PY - 2006/2/15

Y1 - 2006/2/15

N2 - A cationic Au(I) complex catalyzed the cycloisomerization of aromatic enynes that possess a substituent on their alkyne terminus. Cyclization of the 6-endo-dig type proceeded dominantly to give 1,3-di- and 1,2,3-trisubstituted naphthalenes.

AB - A cationic Au(I) complex catalyzed the cycloisomerization of aromatic enynes that possess a substituent on their alkyne terminus. Cyclization of the 6-endo-dig type proceeded dominantly to give 1,3-di- and 1,2,3-trisubstituted naphthalenes.

KW - Catalysis

KW - Cycloisomerization

KW - Enynes

KW - Gold

KW - Indenes

KW - Naphthalenes

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ER -

Cationic Au(I)-catalyzed cycloisomerization of aromatic enynes for the synthesis of substituted naphthalenes

Abstract

Keywords

ASJC Scopus subject areas

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