Charge-transporting property of poly(l,3-phenylenevinylene) containing a nitroxide-substituted phenylamine moiety

Fumiaki Kato; Takashi Kurata; Hiroyuki Nishide; Junji Kido

Charge-transporting property of poly(l,3-phenylenevinylene) containing a nitroxide-substituted phenylamine moiety

Fumiaki Kato^*, Takashi Kurata, Hiroyuki Nishide, Junji Kido

^*Corresponding author for this work

Waseda Research Institute for Science and Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

A new hole-transporting polyradical, poly(4-(N-t-butyl-N-oxyamino) triphenylamine-alt-5-hexyloxy-1,3-phenylenevinylene), was synthesized by Wittig reaction of 4-{N-i-butyl-N-(t-butyldimethylsilyl)oxy}amine-substituted bisformyltriphenylamine and l,3-bis{(triphenylphospho)methyl}benzene dibromide, followed by deprotection and oxidation. Electrochemical or magnetic measurements revealed the electronic structure and charge transporting property of the polyradical.

Original language	English
Title of host publication	Polymer Preprints, Japan
Pages	4107
Number of pages	1
Volume	54
Edition	2
Publication status	Published - 2005
Event	54th SPSJ Symposium on Macromolecules - Yamagata Duration: 2005 Sept 20 → 2005 Sept 22

Other

Other	54th SPSJ Symposium on Macromolecules
City	Yamagata
Period	05/9/20 → 05/9/22

Keywords

Nitroxide
PolyradicalRedox property
Wittig reaction

ASJC Scopus subject areas

Engineering(all)

Cite this

@inproceedings{09f2db13084a46ada47f09c565ac8507,

title = "Charge-transporting property of poly(l,3-phenylenevinylene) containing a nitroxide-substituted phenylamine moiety",

abstract = "A new hole-transporting polyradical, poly(4-(N-t-butyl-N-oxyamino) triphenylamine-alt-5-hexyloxy-1,3-phenylenevinylene), was synthesized by Wittig reaction of 4-{N-i-butyl-N-(t-butyldimethylsilyl)oxy}amine-substituted bisformyltriphenylamine and l,3-bis{(triphenylphospho)methyl}benzene dibromide, followed by deprotection and oxidation. Electrochemical or magnetic measurements revealed the electronic structure and charge transporting property of the polyradical.",

keywords = "Nitroxide, PolyradicalRedox property, Wittig reaction",

author = "Fumiaki Kato and Takashi Kurata and Hiroyuki Nishide and Junji Kido",

year = "2005",

language = "English",

volume = "54",

pages = "4107",

booktitle = "Polymer Preprints, Japan",

edition = "2",

note = "54th SPSJ Symposium on Macromolecules ; Conference date: 20-09-2005 Through 22-09-2005",

}

TY - GEN

T1 - Charge-transporting property of poly(l,3-phenylenevinylene) containing a nitroxide-substituted phenylamine moiety

AU - Kato, Fumiaki

AU - Kurata, Takashi

AU - Nishide, Hiroyuki

AU - Kido, Junji

PY - 2005

Y1 - 2005

N2 - A new hole-transporting polyradical, poly(4-(N-t-butyl-N-oxyamino) triphenylamine-alt-5-hexyloxy-1,3-phenylenevinylene), was synthesized by Wittig reaction of 4-{N-i-butyl-N-(t-butyldimethylsilyl)oxy}amine-substituted bisformyltriphenylamine and l,3-bis{(triphenylphospho)methyl}benzene dibromide, followed by deprotection and oxidation. Electrochemical or magnetic measurements revealed the electronic structure and charge transporting property of the polyradical.

AB - A new hole-transporting polyradical, poly(4-(N-t-butyl-N-oxyamino) triphenylamine-alt-5-hexyloxy-1,3-phenylenevinylene), was synthesized by Wittig reaction of 4-{N-i-butyl-N-(t-butyldimethylsilyl)oxy}amine-substituted bisformyltriphenylamine and l,3-bis{(triphenylphospho)methyl}benzene dibromide, followed by deprotection and oxidation. Electrochemical or magnetic measurements revealed the electronic structure and charge transporting property of the polyradical.

KW - Nitroxide

KW - PolyradicalRedox property

KW - Wittig reaction

UR - http://www.scopus.com/inward/record.url?scp=33645644675&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645644675&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:33645644675

VL - 54

SP - 4107

BT - Polymer Preprints, Japan

T2 - 54th SPSJ Symposium on Macromolecules

Y2 - 20 September 2005 through 22 September 2005

ER -

Charge-transporting property of poly(l,3-phenylenevinylene) containing a nitroxide-substituted phenylamine moiety

Abstract

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Keywords

ASJC Scopus subject areas

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