Conversion of an Aurivillius phase Bi2SrNaNb3O12 into its protonated form via treatment with various mineral acids

Masashi Shirata; Yu Tsunoda; Wataru Sugimoto; Yoshiyuki Sugahara

Conversion of an Aurivillius phase Bi₂SrNaNb₃O₁₂ into its protonated form via treatment with various mineral acids

Masashi Shirata^*, Yu Tsunoda, Wataru Sugimoto, Yoshiyuki Sugahara

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Conference article › peer-review

7 Citations (Scopus)

Abstract

A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi₂SrNaNb₃O₁₂ via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H_1.8[Sr_0.8Bi_0.2NaNb₃O₁₀], while no reactions were observed for HNO₃ and H₂SO₄ under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

Original language	English
Pages (from-to)	GG6241-GG6245
Journal	Materials Research Society Symposium - Proceedings
Volume	658
Publication status	Published - 2001
Event	Solid - State Chemistry of Inorganic Materials III - Boston, MA, United States Duration: 2000 Nov 27 → 2000 Nov 30

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Cite this

@article{a7b443b6042749c8a6ee0e144a461a10,

title = "Conversion of an Aurivillius phase Bi2SrNaNb3O12 into its protonated form via treatment with various mineral acids",

abstract = "A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi2SrNaNb3O12 via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H1.8[Sr0.8Bi0.2NaNb3O10], while no reactions were observed for HNO3 and H2SO4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.",

author = "Masashi Shirata and Yu Tsunoda and Wataru Sugimoto and Yoshiyuki Sugahara",

note = "Funding Information: The authors would like to thank Prof. Kazuyuki Kuroda (Department of Applied Chemistry, Waseda University) for valuable discussion and Mr. Minekazu Fujiwara (Material Characterization Central Laboratory, Waseda University) for his assistance in TEM observation. This work was financially supported partly by the Grant-in-Aid for Scientific Research (No. 10555221) from the Ministry of Education, Science, Sports, and Culture, Japan.; Solid - State Chemistry of Inorganic Materials III ; Conference date: 27-11-2000 Through 30-11-2000",

year = "2001",

language = "English",

volume = "658",

pages = "GG6241--GG6245",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

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TY - JOUR

T1 - Conversion of an Aurivillius phase Bi2SrNaNb3O12 into its protonated form via treatment with various mineral acids

AU - Shirata, Masashi

AU - Tsunoda, Yu

AU - Sugimoto, Wataru

AU - Sugahara, Yoshiyuki

N1 - Funding Information: The authors would like to thank Prof. Kazuyuki Kuroda (Department of Applied Chemistry, Waseda University) for valuable discussion and Mr. Minekazu Fujiwara (Material Characterization Central Laboratory, Waseda University) for his assistance in TEM observation. This work was financially supported partly by the Grant-in-Aid for Scientific Research (No. 10555221) from the Ministry of Education, Science, Sports, and Culture, Japan.

PY - 2001

Y1 - 2001

N2 - A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi2SrNaNb3O12 via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H1.8[Sr0.8Bi0.2NaNb3O10], while no reactions were observed for HNO3 and H2SO4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

AB - A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi2SrNaNb3O12 via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H1.8[Sr0.8Bi0.2NaNb3O10], while no reactions were observed for HNO3 and H2SO4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

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M3 - Conference article

AN - SCOPUS:3142645770

SN - 0272-9172

VL - 658

SP - GG6241-GG6245

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

T2 - Solid - State Chemistry of Inorganic Materials III

Y2 - 27 November 2000 through 30 November 2000

ER -

Conversion of an Aurivillius phase Bi₂SrNaNb₃O₁₂ into its protonated form via treatment with various mineral acids

Abstract

ASJC Scopus subject areas

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