TY - JOUR
T1 - Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond
AU - Yamaguchi, Tadashi
AU - Yoshiya, Kohei
N1 - Funding Information:
This work was supported by Grants-in-Aid for Scientific Research (No. 21550072) from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan.
Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/8/5
Y1 - 2019/8/5
N2 - New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) Å, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) Å, and one metal-metal dative bond, Pt→Hg = 2.6635(7) Å.
AB - New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) Å, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) Å, and one metal-metal dative bond, Pt→Hg = 2.6635(7) Å.
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U2 - 10.1021/acs.inorgchem.9b00978
DO - 10.1021/acs.inorgchem.9b00978
M3 - Article
C2 - 31313571
AN - SCOPUS:85070923669
SN - 0020-1669
VL - 58
SP - 9548
EP - 9552
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 15
ER -