Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex

Masashi Ohkubo; Tokutaro Komatsu; Nobuyuki Matsushita; Norimichi Kojima; Gunzi Saito

doi:10.1080/10587250210746

Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex

Masashi Ohkubo^*, Tokutaro Komatsu, Nobuyuki Matsushita, Norimichi Kojima, Gunzi Saito

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

1 Citation (Scopus)

Abstract

A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl₅(NO)]^2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF⁺ and NO exhibited a photo-induced effect.

Original language	English
Pages (from-to)	147-152
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	376
DOIs	https://doi.org/10.1080/10587250210746
Publication status	Published - 2002
Externally published	Yes
Event	Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States Duration: 2000 Dec 15 → 2000 Dec 18

Keywords

BEDT-TTF
Organic conductors
Photo-induced effect

ASJC Scopus subject areas

Condensed Matter Physics

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10.1080/10587250210746

Cite this

Ohkubo, M., Komatsu, T., Matsushita, N., Kojima, N., & Saito, G. (2002). Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 376, 147-152. https://doi.org/10.1080/10587250210746

Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex. / Ohkubo, Masashi; Komatsu, Tokutaro; Matsushita, Nobuyuki et al.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 376, 2002, p. 147-152.

Research output: Contribution to journal › Conference article › peer-review

Ohkubo, M, Komatsu, T, Matsushita, N, Kojima, N & Saito, G 2002, 'Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 376, pp. 147-152. https://doi.org/10.1080/10587250210746

Ohkubo, Masashi ; Komatsu, Tokutaro ; Matsushita, Nobuyuki et al. / Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex. In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 2002 ; Vol. 376. pp. 147-152.

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abstract = "A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl5(NO)]2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF+ and NO exhibited a photo-induced effect.",

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AU - Komatsu, Tokutaro

AU - Matsushita, Nobuyuki

AU - Kojima, Norimichi

AU - Saito, Gunzi

PY - 2002

Y1 - 2002

N2 - A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl5(NO)]2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF+ and NO exhibited a photo-induced effect.

AB - A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl5(NO)]2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF+ and NO exhibited a photo-induced effect.

KW - BEDT-TTF

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KW - Photo-induced effect

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Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex

Abstract

Keywords

ASJC Scopus subject areas

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