Crystal Structure and Physical Properties of BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene) Salt Coupled with a Photo-Sensitive Transition Metal Complex

Masashi Ohkubo, Tokutaro Komatsu, Nobuyuki Matsushita, Norimichi Kojima, Gunzi Saito

Research output: Contribution to journalArticlepeer-review

Abstract

A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl 5 (NO)] 2− has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF + and NO exhibited a photo-induced effect.

Original languageEnglish
Pages (from-to)147-152
Number of pages6
JournalMolecular Crystals and Liquid Crystals
Volume376
Issue number1
DOIs
Publication statusPublished - 2002
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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