Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand

Kenichi Oyaizu; Eishun Tsuchida

doi:10.1016/S0020-1693(03)00311-6

Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand

Kenichi Oyaizu, Eishun Tsuchida^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Crystal structure of [Fe(salphen)Cl] (H₂salphen=N,N′-(1R, 2R)-1,2-diphenylethylenebis(salicylideneimine)) reveals that a steric effect induced by the bulky substituent on the Schiff base ligand brings about drastic changes in the reactivity of the complex; the typical dimerization of the chloroiron(III) complex upon basification to yield μ-oxo complexes are suppressed, resulting in the high-yielding conversion to a hydroxide salt.

Original language	English
Pages (from-to)	414-419
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	355
DOIs	https://doi.org/10.1016/S0020-1693(03)00311-6
Publication status	Published - 2003 Nov 20

Keywords

Chloroiron complexes
Crystal structures
Schiff base ligands

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(03)00311-6

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title = "Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand",

abstract = "Crystal structure of [Fe(salphen)Cl] (H2salphen=N,N′-(1R, 2R)-1,2-diphenylethylenebis(salicylideneimine)) reveals that a steric effect induced by the bulky substituent on the Schiff base ligand brings about drastic changes in the reactivity of the complex; the typical dimerization of the chloroiron(III) complex upon basification to yield μ-oxo complexes are suppressed, resulting in the high-yielding conversion to a hydroxide salt.",

keywords = "Chloroiron complexes, Crystal structures, Schiff base ligands",

author = "Kenichi Oyaizu and Eishun Tsuchida",

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T1 - Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand

AU - Oyaizu, Kenichi

AU - Tsuchida, Eishun

PY - 2003/11/20

Y1 - 2003/11/20

N2 - Crystal structure of [Fe(salphen)Cl] (H2salphen=N,N′-(1R, 2R)-1,2-diphenylethylenebis(salicylideneimine)) reveals that a steric effect induced by the bulky substituent on the Schiff base ligand brings about drastic changes in the reactivity of the complex; the typical dimerization of the chloroiron(III) complex upon basification to yield μ-oxo complexes are suppressed, resulting in the high-yielding conversion to a hydroxide salt.

AB - Crystal structure of [Fe(salphen)Cl] (H2salphen=N,N′-(1R, 2R)-1,2-diphenylethylenebis(salicylideneimine)) reveals that a steric effect induced by the bulky substituent on the Schiff base ligand brings about drastic changes in the reactivity of the complex; the typical dimerization of the chloroiron(III) complex upon basification to yield μ-oxo complexes are suppressed, resulting in the high-yielding conversion to a hydroxide salt.

KW - Chloroiron complexes

KW - Crystal structures

KW - Schiff base ligands

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AN - SCOPUS:1042299772

SN - 0020-1693

VL - 355

SP - 414

EP - 419

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand

Abstract

Keywords

ASJC Scopus subject areas

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