Abstract
We have designed and synthesized a large number of donor-acceptor type organic electrochromic (EC) materials to increase the resistance to ultraviolet irradiation. The guiding principle for the molecular design is given briefly. One of the materials is a viologen-ferrocene EC material. In this paper, we report two different types of electrochromic windows (ECWs): one is fabricated with a viologen-ferrocene EC material, and the other with a carbon-based electrode. The coloration process of the viologen-based ECW is also discussed with reference to the driving voltage dependence. Outdoor weathering tests were carried out on ECWs designed for automotive applications. The 2-year outdoor weathering tests suggest a potentially high durability.
Original language | English |
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Pages (from-to) | 209-216 |
Number of pages | 8 |
Journal | Solid State Ionics |
Volume | 165 |
Issue number | 1-4 |
DOIs | |
Publication status | Published - 2003 Dec |
Externally published | Yes |
Keywords
- Carbon-based counter electrode
- Donor-acceptor type organic electrochromic material
- Electrochromic window
- Outdoor weathering tests
- Ultraviolet irradiation
ASJC Scopus subject areas
- Electrochemistry
- Physical and Theoretical Chemistry
- Energy Engineering and Power Technology
- Materials Chemistry
- Condensed Matter Physics