Decarbonylative C-H coupling of azoles and aryl esters: Unprecedented nickel catalysis and application to the synthesis of muscoride A

Kazuma Amaike; Kei Muto; Junichiro Yamaguchi; Kenichiro Itami

doi:10.1021/ja306062c

Decarbonylative C-H coupling of azoles and aryl esters: Unprecedented nickel catalysis and application to the synthesis of muscoride A

Kazuma Amaike, Kei Muto, Junichiro Yamaguchi^*, Kenichiro Itami

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

292 Citations (Scopus)

Abstract

A nickel-catalyzed decarbonylative C-H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of expensive metal catalysts or silver- or copper-based stoichiometric oxidants. We have successfully applied this new C-H arylation reaction to a convergent formal synthesis of muscoride A.

Original language	English
Pages (from-to)	13573-13576
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	33
DOIs	https://doi.org/10.1021/ja306062c
Publication status	Published - 2012 Aug 22
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja306062c

Cite this

@article{58d8037578274812b241606d66ae963a,

title = "Decarbonylative C-H coupling of azoles and aryl esters: Unprecedented nickel catalysis and application to the synthesis of muscoride A",

abstract = "A nickel-catalyzed decarbonylative C-H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of expensive metal catalysts or silver- or copper-based stoichiometric oxidants. We have successfully applied this new C-H arylation reaction to a convergent formal synthesis of muscoride A.",

author = "Kazuma Amaike and Kei Muto and Junichiro Yamaguchi and Kenichiro Itami",

year = "2012",

month = aug,

day = "22",

doi = "10.1021/ja306062c",

language = "English",

volume = "134",

pages = "13573--13576",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "33",

}

TY - JOUR

T1 - Decarbonylative C-H coupling of azoles and aryl esters

T2 - Unprecedented nickel catalysis and application to the synthesis of muscoride A

AU - Amaike, Kazuma

AU - Muto, Kei

AU - Yamaguchi, Junichiro

AU - Itami, Kenichiro

PY - 2012/8/22

Y1 - 2012/8/22

N2 - A nickel-catalyzed decarbonylative C-H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of expensive metal catalysts or silver- or copper-based stoichiometric oxidants. We have successfully applied this new C-H arylation reaction to a convergent formal synthesis of muscoride A.

AB - A nickel-catalyzed decarbonylative C-H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of expensive metal catalysts or silver- or copper-based stoichiometric oxidants. We have successfully applied this new C-H arylation reaction to a convergent formal synthesis of muscoride A.

UR - http://www.scopus.com/inward/record.url?scp=84865430497&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84865430497&partnerID=8YFLogxK

U2 - 10.1021/ja306062c

DO - 10.1021/ja306062c

M3 - Article

C2 - 22870867

AN - SCOPUS:84865430497

SN - 0002-7863

VL - 134

SP - 13573

EP - 13576

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 33

ER -

Decarbonylative C-H coupling of azoles and aryl esters: Unprecedented nickel catalysis and application to the synthesis of muscoride A

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this