Design and synthesis of photoresponsive poly(benzyl ester) dendrimers with all-azobenzene repeating units

Shuangxi Wang; Rigoberto C. Advincula

doi:10.1021/ol0165591

Design and synthesis of photoresponsive poly(benzyl ester) dendrimers with all-azobenzene repeating units

Shuangxi Wang, Rigoberto C. Advincula^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

equation presented A novel class of dendrons and dendrimers containing all-azobenzene units (up to 29 azobenzene groups) was designed and synthesized by the convergent method using a protected orthogonal AB₂ monomer (10) and tetra-functionalized core (11) as building blocks. The preparation of the key monomer (10) involved condensation of a protected nitroso compound (9) and 5-aminoisophthalic acid. These are the first examples of photoresponsive dendrimers with all-azobenzene repeating units.

Original language	English
Pages (from-to)	3831-3833
Number of pages	3
Journal	Organic Letters
Volume	3
Issue number	24
DOIs	https://doi.org/10.1021/ol0165591
Publication status	Published - 2001 Nov 29
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0165591

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abstract = "equation presented A novel class of dendrons and dendrimers containing all-azobenzene units (up to 29 azobenzene groups) was designed and synthesized by the convergent method using a protected orthogonal AB2 monomer (10) and tetra-functionalized core (11) as building blocks. The preparation of the key monomer (10) involved condensation of a protected nitroso compound (9) and 5-aminoisophthalic acid. These are the first examples of photoresponsive dendrimers with all-azobenzene repeating units.",

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AB - equation presented A novel class of dendrons and dendrimers containing all-azobenzene units (up to 29 azobenzene groups) was designed and synthesized by the convergent method using a protected orthogonal AB2 monomer (10) and tetra-functionalized core (11) as building blocks. The preparation of the key monomer (10) involved condensation of a protected nitroso compound (9) and 5-aminoisophthalic acid. These are the first examples of photoresponsive dendrimers with all-azobenzene repeating units.

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Design and synthesis of photoresponsive poly(benzyl ester) dendrimers with all-azobenzene repeating units

Abstract

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