TY - JOUR
T1 - Dinuclear manganese(II) complex containing tetrakis(2-pyridyl)methane as a spiro-fused bridge
AU - Okazawa, Atsushi
AU - Ishida, Takayuki
AU - Nogami, Takashi
PY - 2004/11/5
Y1 - 2004/11/5
N2 - A dinuclear manganese(II) complex [{Mn(hfac)2} 2(py4C)] was synthesized, where hfac and py4C denote 1,1,1,5,5,5-hexafluoropentane-2,4-dionate and tetrakis(2-pyridyl)methane, respectively. X-Ray crystallographic analysis revealed that the dihedral angle was 87.4(2)° between two chelate rings around the spiro center. Very weak antiferromagnetic interaction is operative between manganese(II) spins.
AB - A dinuclear manganese(II) complex [{Mn(hfac)2} 2(py4C)] was synthesized, where hfac and py4C denote 1,1,1,5,5,5-hexafluoropentane-2,4-dionate and tetrakis(2-pyridyl)methane, respectively. X-Ray crystallographic analysis revealed that the dihedral angle was 87.4(2)° between two chelate rings around the spiro center. Very weak antiferromagnetic interaction is operative between manganese(II) spins.
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U2 - 10.1246/cl.2004.1478
DO - 10.1246/cl.2004.1478
M3 - Article
AN - SCOPUS:13544264700
SN - 0366-7022
VL - 33
SP - 1478
EP - 1479
JO - Chemistry Letters
JF - Chemistry Letters
IS - 11
ER -