DMAP-accelerated rhodium(I) chloride catalyzed hydroboration of vinylarenes

Kohei Endo; Munenao Hirokami; Kazunari Takeuchi; Takanori Shibata

doi:10.1055/s-0028-1087415

DMAP-accelerated rhodium(I) chloride catalyzed hydroboration of vinylarenes

Kohei Endo^*, Munenao Hirokami, Kazunari Takeuchi, Takanori Shibata

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Regioselective hydroboration of vinylarenes catalyzed by a Rh(I)-DPPB complex proceeded rapidly when DMAP was used as an additive. The catalyst loading could be reduced to 0.4 mol% Rh(I) to furnish the desired products in good to excellent yield with high regioselectivity.

Original language	English
Pages (from-to)	3231-3233
Number of pages	3
Journal	Synlett
Issue number	20
DOIs	https://doi.org/10.1055/s-0028-1087415
Publication status	Published - 2008 Dec 16

Keywords

Alkenes
Boron
Hydroborations
Regioselectivity
Rhodium

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0028-1087415

Cite this

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abstract = "Regioselective hydroboration of vinylarenes catalyzed by a Rh(I)-DPPB complex proceeded rapidly when DMAP was used as an additive. The catalyst loading could be reduced to 0.4 mol% Rh(I) to furnish the desired products in good to excellent yield with high regioselectivity.",

keywords = "Alkenes, Boron, Hydroborations, Regioselectivity, Rhodium",

author = "Kohei Endo and Munenao Hirokami and Kazunari Takeuchi and Takanori Shibata",

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day = "16",

doi = "10.1055/s-0028-1087415",

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T1 - DMAP-accelerated rhodium(I) chloride catalyzed hydroboration of vinylarenes

AU - Endo, Kohei

AU - Hirokami, Munenao

AU - Takeuchi, Kazunari

AU - Shibata, Takanori

PY - 2008/12/16

Y1 - 2008/12/16

N2 - Regioselective hydroboration of vinylarenes catalyzed by a Rh(I)-DPPB complex proceeded rapidly when DMAP was used as an additive. The catalyst loading could be reduced to 0.4 mol% Rh(I) to furnish the desired products in good to excellent yield with high regioselectivity.

AB - Regioselective hydroboration of vinylarenes catalyzed by a Rh(I)-DPPB complex proceeded rapidly when DMAP was used as an additive. The catalyst loading could be reduced to 0.4 mol% Rh(I) to furnish the desired products in good to excellent yield with high regioselectivity.

KW - Alkenes

KW - Boron

KW - Hydroborations

KW - Regioselectivity

KW - Rhodium

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ER -

DMAP-accelerated rhodium(I) chloride catalyzed hydroboration of vinylarenes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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