Dynamic hemicarcerands and hemicarceplexes

Stephen Ro; Stuart J. Rowan; Anthony R. Pease; Donald J. Cram; J. Fraser Stoddart

Dynamic hemicarcerands and hemicarceplexes

Stephen Ro, Stuart J. Rowan, Anthony R. Pease, Donald J. Cram, J. Fraser Stoddart^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

(equation presented) The reversible nature of the imine bond formation in CDCl₃ solution has been exploited to exchange substituted for unsubstituted m-phenylenediamine (MPD) units in hemicarcerand octaimines. Moreover, acid-catalyzed imine exchange has been shown to provide a novel mechanism whereby ferrocene (Fc) can be released as an entrapped guest from the hemicarceplex C₂B₄⊙Fc dissolved in CDCl₃ to give the hemicarcerand C₂B₄ when excess of both MPD and trifluoroacetic acid are present.

Original language	English
Pages (from-to)	2411-2414
Number of pages	4
Journal	Organic Letters
Volume	2
Issue number	16
Publication status	Published - 2000 Aug 10
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

Cite this

@article{87d3df0efc9a40468e8379fab3b311cf,

title = "Dynamic hemicarcerands and hemicarceplexes",

abstract = "(equation presented) The reversible nature of the imine bond formation in CDCl3 solution has been exploited to exchange substituted for unsubstituted m-phenylenediamine (MPD) units in hemicarcerand octaimines. Moreover, acid-catalyzed imine exchange has been shown to provide a novel mechanism whereby ferrocene (Fc) can be released as an entrapped guest from the hemicarceplex C2B4⊙Fc dissolved in CDCl3 to give the hemicarcerand C2B4 when excess of both MPD and trifluoroacetic acid are present.",

author = "Stephen Ro and Rowan, {Stuart J.} and Pease, {Anthony R.} and Cram, {Donald J.} and Stoddart, {J. Fraser}",

year = "2000",

month = aug,

day = "10",

language = "English",

volume = "2",

pages = "2411--2414",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "16",

}

TY - JOUR

T1 - Dynamic hemicarcerands and hemicarceplexes

AU - Ro, Stephen

AU - Rowan, Stuart J.

AU - Pease, Anthony R.

AU - Cram, Donald J.

AU - Stoddart, J. Fraser

PY - 2000/8/10

Y1 - 2000/8/10

N2 - (equation presented) The reversible nature of the imine bond formation in CDCl3 solution has been exploited to exchange substituted for unsubstituted m-phenylenediamine (MPD) units in hemicarcerand octaimines. Moreover, acid-catalyzed imine exchange has been shown to provide a novel mechanism whereby ferrocene (Fc) can be released as an entrapped guest from the hemicarceplex C2B4⊙Fc dissolved in CDCl3 to give the hemicarcerand C2B4 when excess of both MPD and trifluoroacetic acid are present.

AB - (equation presented) The reversible nature of the imine bond formation in CDCl3 solution has been exploited to exchange substituted for unsubstituted m-phenylenediamine (MPD) units in hemicarcerand octaimines. Moreover, acid-catalyzed imine exchange has been shown to provide a novel mechanism whereby ferrocene (Fc) can be released as an entrapped guest from the hemicarceplex C2B4⊙Fc dissolved in CDCl3 to give the hemicarcerand C2B4 when excess of both MPD and trifluoroacetic acid are present.

UR - http://www.scopus.com/inward/record.url?scp=0034632438&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034632438&partnerID=8YFLogxK

M3 - Article

C2 - 10956509

AN - SCOPUS:0034632438

SN - 1523-7060

VL - 2

SP - 2411

EP - 2414

JO - Organic Letters

JF - Organic Letters

IS - 16

ER -

Dynamic hemicarcerands and hemicarceplexes

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this