Effect of carbon dioxide on lithium anode cycleability with various substrates

Tetsuya Osaka; Toshiyuki Momma; Yasuhiro Matsumoto; Yuji Uchida

doi:10.1016/S0378-7753(97)02596-2

Effect of carbon dioxide on lithium anode cycleability with various substrates

Tetsuya Osaka^*, Toshiyuki Momma, Yasuhiro Matsumoto, Yuji Uchida

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

The effect on the enhancement of the charge/discharge behavior of electrodeposited lithium metal on various substrates with CO₂ was investigated in LiClO₄/propylene carbonate electrolyte. The lithium cycleability was enhanced with CO₂ addition to the electrolyte solution when using nickel and titanium substrates, whereas no apparent enhancement was observed with copper and silver substrates. The results obtained from voltammetry indicated that the reduction of CO₂ did not occur on nickel and titanium, but on copper and silver. It is suggested that the enhancement with CO₂ addition is effective with the substrates which do not reduce CO₂ in the electrolyte before lithium deposition.

Original language	English
Pages (from-to)	497-500
Number of pages	4
Journal	Journal of Power Sources
Volume	68
Issue number	2
DOIs	https://doi.org/10.1016/S0378-7753(97)02596-2
Publication status	Published - 1997 Oct

Keywords

Carbon dioxide
Cycleability
Lithium anodes

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/S0378-7753(97)02596-2

Cite this

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title = "Effect of carbon dioxide on lithium anode cycleability with various substrates",

abstract = "The effect on the enhancement of the charge/discharge behavior of electrodeposited lithium metal on various substrates with CO2 was investigated in LiClO4/propylene carbonate electrolyte. The lithium cycleability was enhanced with CO2 addition to the electrolyte solution when using nickel and titanium substrates, whereas no apparent enhancement was observed with copper and silver substrates. The results obtained from voltammetry indicated that the reduction of CO2 did not occur on nickel and titanium, but on copper and silver. It is suggested that the enhancement with CO2 addition is effective with the substrates which do not reduce CO2 in the electrolyte before lithium deposition.",

keywords = "Carbon dioxide, Cycleability, Lithium anodes",

author = "Tetsuya Osaka and Toshiyuki Momma and Yasuhiro Matsumoto and Yuji Uchida",

year = "1997",

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doi = "10.1016/S0378-7753(97)02596-2",

language = "English",

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pages = "497--500",

journal = "Journal of Power Sources",

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TY - JOUR

T1 - Effect of carbon dioxide on lithium anode cycleability with various substrates

AU - Osaka, Tetsuya

AU - Momma, Toshiyuki

AU - Matsumoto, Yasuhiro

AU - Uchida, Yuji

PY - 1997/10

Y1 - 1997/10

N2 - The effect on the enhancement of the charge/discharge behavior of electrodeposited lithium metal on various substrates with CO2 was investigated in LiClO4/propylene carbonate electrolyte. The lithium cycleability was enhanced with CO2 addition to the electrolyte solution when using nickel and titanium substrates, whereas no apparent enhancement was observed with copper and silver substrates. The results obtained from voltammetry indicated that the reduction of CO2 did not occur on nickel and titanium, but on copper and silver. It is suggested that the enhancement with CO2 addition is effective with the substrates which do not reduce CO2 in the electrolyte before lithium deposition.

AB - The effect on the enhancement of the charge/discharge behavior of electrodeposited lithium metal on various substrates with CO2 was investigated in LiClO4/propylene carbonate electrolyte. The lithium cycleability was enhanced with CO2 addition to the electrolyte solution when using nickel and titanium substrates, whereas no apparent enhancement was observed with copper and silver substrates. The results obtained from voltammetry indicated that the reduction of CO2 did not occur on nickel and titanium, but on copper and silver. It is suggested that the enhancement with CO2 addition is effective with the substrates which do not reduce CO2 in the electrolyte before lithium deposition.

KW - Carbon dioxide

KW - Cycleability

KW - Lithium anodes

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U2 - 10.1016/S0378-7753(97)02596-2

DO - 10.1016/S0378-7753(97)02596-2

M3 - Article

AN - SCOPUS:0031246572

SN - 0378-7753

VL - 68

SP - 497

EP - 500

JO - Journal of Power Sources

JF - Journal of Power Sources

IS - 2

ER -

Effect of carbon dioxide on lithium anode cycleability with various substrates

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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