Electrochemical Activity of Nitrogen-Containing Groups in Organic Electrode Materials and Related Improvement Strategies

Qianchuan Yu, Zhihuan Xue, Meichen Li, Peimeng Qiu, Changgang Li, Shengping Wang*, Jingxian Yu, Hiroki Nara, Jongbeom Na, Yusuke Yamauchi

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

34 Citations (Scopus)


In recent years, due to their structural diversity, adjustability, versatility, and excellent electrochemical properties, organic compounds with nitrogen-containing groups (OCNs) have become some of the most promising organic electrode materials. The nitrogen-containing groups acting as electrochemical active sites include carbon–nitrogen groups, nitrogen–nitrogen groups, nitrogen–oxygen groups in OCNs, and nitrogen-containing groups in covalent organic frameworks. The molecular structure regulation of OCNs with nitrogen-containing groups acting as electrochemical active centers can suppress dissolution in electrolytes, increase electronic conductivity, and improve the kinetics of redox reactions. The kinetics behavior and electrochemical characteristics of OCN electrode materials in alkali metal rechargeable batteries with organic electrolytes are reviewed, and the related relationships between the structure and electrochemical properties of OCNs are the core of this review. Herein, the electrochemical reaction mechanisms and the strategies to improve the electrochemical activity of nitrogen-containing groups in OCNs are clarified, and the conjugate molecular structure of OCNs is shown to be an important direction for improvement. These results will have implications for research on electrode materials and provide more choices for rechargeable batteries. Moreover, this work will guide the study of more efficient OCNs that can be used as electrode materials.

Original languageEnglish
Article number2002523
JournalAdvanced Energy Materials
Issue number7
Publication statusPublished - 2021 Feb 18


  • covalent organic frameworks
  • electrochemical activity
  • electrode materials
  • nitrogen-containing groups

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)


Dive into the research topics of 'Electrochemical Activity of Nitrogen-Containing Groups in Organic Electrode Materials and Related Improvement Strategies'. Together they form a unique fingerprint.

Cite this