Electrochemical Mg2+ intercalation into a bimetallic CuFe Prussian blue analog in aqueous electrolytes

Yoshifumi Mizuno; Masashi Okubo; Eiji Hosono; Tetsuichi Kudo; Katsuyoshi Oh-Ishi; Atsushi Okazawa; Norimichi Kojima; Ryosuke Kurono; Shin Ichi Nishimura; Atsuo Yamada

doi:10.1039/c3ta13205f

Electrochemical Mg²⁺ intercalation into a bimetallic CuFe Prussian blue analog in aqueous electrolytes

Yoshifumi Mizuno, Masashi Okubo^*, Eiji Hosono, Tetsuichi Kudo, Katsuyoshi Oh-Ishi, Atsushi Okazawa, Norimichi Kojima, Ryosuke Kurono, Shin Ichi Nishimura, Atsuo Yamada

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

144 Citations (Scopus)

Abstract

Mg²⁺ intercalation/deintercalation is achieved by using aqueous electrolytes and Prussian blue analog electrodes. Ex situ X-ray diffraction evidenced the solid solution process of Mg²⁺ intercalation/ deintercalation, while the ⁵⁷Fe Mössbauer spectroscopy and X-ray absorption near edge structure revealed redox of both Cu and Fe.

Original language	English
Pages (from-to)	13055-13059
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	1
Issue number	42
DOIs	https://doi.org/10.1039/c3ta13205f
Publication status	Published - 2013 Nov 14
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Renewable Energy, Sustainability and the Environment
Materials Science(all)

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/c3ta13205f

Cite this

@article{0c0e363999924f0e9729454c82d7ee28,

title = "Electrochemical Mg2+ intercalation into a bimetallic CuFe Prussian blue analog in aqueous electrolytes",

abstract = "Mg2+ intercalation/deintercalation is achieved by using aqueous electrolytes and Prussian blue analog electrodes. Ex situ X-ray diffraction evidenced the solid solution process of Mg2+ intercalation/ deintercalation, while the 57Fe M{\"o}ssbauer spectroscopy and X-ray absorption near edge structure revealed redox of both Cu and Fe.",

author = "Yoshifumi Mizuno and Masashi Okubo and Eiji Hosono and Tetsuichi Kudo and Katsuyoshi Oh-Ishi and Atsushi Okazawa and Norimichi Kojima and Ryosuke Kurono and Nishimura, {Shin Ichi} and Atsuo Yamada",

year = "2013",

month = nov,

day = "14",

doi = "10.1039/c3ta13205f",

language = "English",

volume = "1",

pages = "13055--13059",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

number = "42",

}

TY - JOUR

T1 - Electrochemical Mg2+ intercalation into a bimetallic CuFe Prussian blue analog in aqueous electrolytes

AU - Mizuno, Yoshifumi

AU - Okubo, Masashi

AU - Hosono, Eiji

AU - Kudo, Tetsuichi

AU - Oh-Ishi, Katsuyoshi

AU - Okazawa, Atsushi

AU - Kojima, Norimichi

AU - Kurono, Ryosuke

AU - Nishimura, Shin Ichi

AU - Yamada, Atsuo

PY - 2013/11/14

Y1 - 2013/11/14

N2 - Mg2+ intercalation/deintercalation is achieved by using aqueous electrolytes and Prussian blue analog electrodes. Ex situ X-ray diffraction evidenced the solid solution process of Mg2+ intercalation/ deintercalation, while the 57Fe Mössbauer spectroscopy and X-ray absorption near edge structure revealed redox of both Cu and Fe.

AB - Mg2+ intercalation/deintercalation is achieved by using aqueous electrolytes and Prussian blue analog electrodes. Ex situ X-ray diffraction evidenced the solid solution process of Mg2+ intercalation/ deintercalation, while the 57Fe Mössbauer spectroscopy and X-ray absorption near edge structure revealed redox of both Cu and Fe.

UR - http://www.scopus.com/inward/record.url?scp=84885902207&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84885902207&partnerID=8YFLogxK

U2 - 10.1039/c3ta13205f

DO - 10.1039/c3ta13205f

M3 - Article

AN - SCOPUS:84885902207

SN - 2050-7488

VL - 1

SP - 13055

EP - 13059

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 42

ER -