Electrochemical response of electrodes coated with lysine-styrene block copolymers with microphase-separated structures

Eishun Tsuchida, Hiroyuki Nishide, Naoshi Ishimaru, Donald D. Montgomery, Fred C. Anson*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Three new block copolymers for preparing polyelectrolyte coatings on electrode surfaces are described. These copolymers are shown to adopt microphase-separated structures in the solid state in which hydrophibic and hydrophobic blocks form discrete domains. The details of the domain morphology appear to determine the ion-exchange behavior and electrochemical response of the coatings. The wide range of microphase-separated structures available with coatings cast from block copolymers offers attractive possibilities in studies of morphological control of coating behavior.

Original languageEnglish
Pages (from-to)2898-2902
Number of pages5
JournalJournal of Physical Chemistry
Volume91
Issue number11
Publication statusPublished - 1987

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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