Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

Taishi Yokoi; Shingo Machida; Yoshiyuki Sugahara; Masami Hashimoto; Satoshi Kitaoka

doi:10.1039/c7cc01169e

Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

Taishi Yokoi^*, Shingo Machida, Yoshiyuki Sugahara, Masami Hashimoto, Satoshi Kitaoka

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(-)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.

Original language	English
Pages (from-to)	6524-6527
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	48
DOIs	https://doi.org/10.1039/c7cc01169e
Publication status	Published - 2017 Jan 1

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(-)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.",

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AU - Machida, Shingo

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AU - Hashimoto, Masami

AU - Kitaoka, Satoshi

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AB - Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(-)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.

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Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

Abstract

ASJC Scopus subject areas

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