Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers

Takanori Shibata; Mayumi Otomo; Kohei Endo

doi:10.1055/s-0029-1219815

Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers

Takanori Shibata^*, Mayumi Otomo, Kohei Endo

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.

Original language	English
Article number	U00910ST
Pages (from-to)	1235-1238
Number of pages	4
Journal	Synlett
Issue number	8
DOIs	https://doi.org/10.1055/s-0029-1219815
Publication status	Published - 2010 May 14

Keywords

Catalysis
Chirality
Cycloaddition
Multicyclic
Rhodium

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1055/s-0029-1219815

Cite this

@article{ec7b8abb55e5438fb1d8ea7cc2c2b8da,

title = "Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers",

abstract = "A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.",

keywords = "Catalysis, Chirality, Cycloaddition, Multicyclic, Rhodium",

author = "Takanori Shibata and Mayumi Otomo and Kohei Endo",

year = "2010",

month = may,

day = "14",

doi = "10.1055/s-0029-1219815",

language = "English",

pages = "1235--1238",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "8",

}

TY - JOUR

T1 - Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers

AU - Shibata, Takanori

AU - Otomo, Mayumi

AU - Endo, Kohei

PY - 2010/5/14

Y1 - 2010/5/14

N2 - A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.

AB - A chiral rhodium catalyst realized the first intramolecular [2+2+2] cycloaddition of yne-ene-enes, and chiral multicyclic cyclohexenes with adjacent three chiral centers were afforded with high to excellent ee.

KW - Catalysis

KW - Chirality

KW - Cycloaddition

KW - Multicyclic

KW - Rhodium

UR - http://www.scopus.com/inward/record.url?scp=77952082333&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77952082333&partnerID=8YFLogxK

U2 - 10.1055/s-0029-1219815

DO - 10.1055/s-0029-1219815

M3 - Article

AN - SCOPUS:77952082333

SN - 0936-5214

SP - 1235

EP - 1238

JO - Synlett

JF - Synlett

IS - 8

M1 - U00910ST

ER -

Enantioselective intramolecular [2+2+2] cycloaddition of dienynes for the construction of adjacent three chiral centers

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this