@article{4d73722b8e984c27974b1772ecabce7c,
title = "Enantioselective Mukaiyama-Michael Reaction of Cyclic α-Alkylidene β-Keto Phosphine Oxide and Phosphonate and Asymmetric Synthesis of (R)-Homosarkomycin",
abstract = "The asymmetric Mukaiyama-Michael reaction of cyclic α-alkylidene β-oxo phosphates and phosphine oxides that proceeds in a highly enantioselective manner is described. It is possible to carry out these reactions using a catalytic amount of a bisoxazoline-Cu(II) complex without decreasing the enantioselectivity, and one of the products has been successfully used for the first enantioselective synthesis of (R)-homosarkomycin.",
author = "Kotaro Nagatani and Atsushi Minami and Haruka Tezuka and Yunosuke Hoshino and Masahisa Nakada",
note = "Funding Information: We acknowledge support from the Materials Characterization Central Laboratory, Waseda University, for characterization of new compounds. This work was financially supported in part by a Grant-in-Aid for Scientific Research on Innovative Areas 2707 Middle molecular strategy from MEXT and a Waseda University Grant for Special Research Projects. Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",
year = "2017",
month = feb,
day = "17",
doi = "10.1021/acs.orglett.6b03798",
language = "English",
volume = "19",
pages = "810--813",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "4",
}