@article{3db72e8e3a234c73b8a188717fa20f8e,
title = "Enantioselective synthesis of planar-chiral phosphines with 1,n-dioxa[n]paracyclophane scaffold and their application as chiral ligands",
abstract = "A new family of chiral phosphines based on planar-chiral 1,n-dioxa[n]paracyclophane scaffold was created. They were synthesized with excellent enantioselectivity via asymmetric ortho-lithiation using sec-butyllithium and (-)-sparteine. These phosphines were used as chiral ligands in three reactions: Ag-catalyzed allylation of imines, Pd-catalyzed asymmetric Sonogashira coupling of diiodoparacyclophanes, and Pd-catalyzed asymmetric Suzuki-Miyaura coupling of tricarbonyl(η6-ortho-dichlorobenzene)chromium.",
author = "Kazumasa Kanda and Shoya Oshima and Tsubasa Shizuno and Risa Hamanaka and Miku Fukai and Takanori Shibata",
note = "Funding Information: K. Kanda is grateful to the Japan Society for the Promotion of Science for the fellowship support. This work was supported by Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology, Japan (No. 23655091). We also thank Asahi Glass Foundation, the Global COE program 'Center for Practice Chemical Wisdom' by MEXT, and ACT-C. We also express our thanks to Dr. Takashi Otani (Waseda Univ.) for general support for this project. Funding Information: K. Kanda is grateful to the Japan Society for the Promotion of Science for the fellowship support. This Funding Information: work was supported by Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Publisher Copyright: {\textcopyright} 2014 The Japan Institute of Heterocyclic Chemistry.",
year = "2014",
doi = "10.3987/COM-13-S(S)105",
language = "English",
volume = "8",
pages = "1355--1370",
journal = "Heterocycles",
issn = "0385-5414",
publisher = "Japan Institute of Heterocyclic Chemistry",
number = "2",
}