TY - JOUR
T1 - Enhanced oxygen permeation through a porous glass membrane containing phthalocyanato- and porphyrinato-cobalt complexes as an oxygen carrier
AU - Preethi, Nalinakumari
AU - Shinohara, Hiromi
AU - Nishide, Hiroyuki
PY - 2006
Y1 - 2006
N2 - The pore surface of a porous glass membrane was modified with phthalocyanato- and tetraphenylporphyrinato-1-(benzylimidazole)cobalt(II) complexes, which specifically and reversibly binds molecular oxygen from air. The lower oxygen-binding affinity enhanced surface oxygen diffusion which improved permeability (3:0 × 10 -11 kmol m s -1 m -2 kPa -1) and (oxygen/nitrogen) permselectivity (10).
AB - The pore surface of a porous glass membrane was modified with phthalocyanato- and tetraphenylporphyrinato-1-(benzylimidazole)cobalt(II) complexes, which specifically and reversibly binds molecular oxygen from air. The lower oxygen-binding affinity enhanced surface oxygen diffusion which improved permeability (3:0 × 10 -11 kmol m s -1 m -2 kPa -1) and (oxygen/nitrogen) permselectivity (10).
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U2 - 10.1246/bcsj.79.1308
DO - 10.1246/bcsj.79.1308
M3 - Article
AN - SCOPUS:33750620500
SN - 0009-2673
VL - 79
SP - 1308
EP - 1311
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 8
ER -