TY - JOUR
T1 - Enzymatic reduction of synthetic polymer-bound hemin derivatives
T2 - efficient method to prepare a heme-oxygen adduct in cooled aqueous medium
AU - Uotani, Nobuo
AU - Hasegawa, Etsuo
AU - Nishide, Hiroyuki
AU - Tsuchida, Eishun
PY - 1984
Y1 - 1984
N2 - Synthetic polymer-bound hemin (iron(III) protoporphyrin IX) derivatives were effectively reduced by ferredoxin and ferredoxin-NADP reductase system. The resultant polymer-bound heme (iron(II) protoporphyrin IX) derivatives formed oxygen adducts with a lifetime of ca. 1 hr in aqueous solution at -30°C. The reduction rate is discussed in terms of the structure of the hemin derivatives.
AB - Synthetic polymer-bound hemin (iron(III) protoporphyrin IX) derivatives were effectively reduced by ferredoxin and ferredoxin-NADP reductase system. The resultant polymer-bound heme (iron(II) protoporphyrin IX) derivatives formed oxygen adducts with a lifetime of ca. 1 hr in aqueous solution at -30°C. The reduction rate is discussed in terms of the structure of the hemin derivatives.
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U2 - 10.1016/0162-0134(84)80017-3
DO - 10.1016/0162-0134(84)80017-3
M3 - Article
C2 - 6502161
AN - SCOPUS:0021508971
SN - 0162-0134
VL - 22
SP - 85
EP - 89
JO - Journal of Inorganic Biochemistry
JF - Journal of Inorganic Biochemistry
IS - 2
ER -