Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins

Isao Shimizu; Munetsugu Fujita; Takayuki Nakajima; Tadashi Sato

Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins

Isao Shimizu^*, Munetsugu Fujita, Takayuki Nakajima, Tadashi Sato

^*Corresponding author for this work

Waseda University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Reaction of trisubstituted cyclic olefins with NaN₃ in the presence of Cu(OTf)₂ upon irradiation under oxygen gave keto nitriles in good yields. 1,5-Dimethyl-1,5-cyclooctadiene and 1,5,9-trimethyl-1,5,9-cyclododecatriene were converted into the corresponding unsaturated keto nitriles.

Original language	English
Pages (from-to)	887-888
Number of pages	2
Journal	Synlett
Volume	1997
Issue number	8
Publication status	Published - 1997

ASJC Scopus subject areas

Organic Chemistry

Cite this

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title = "Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins",

abstract = "Reaction of trisubstituted cyclic olefins with NaN3 in the presence of Cu(OTf)2 upon irradiation under oxygen gave keto nitriles in good yields. 1,5-Dimethyl-1,5-cyclooctadiene and 1,5,9-trimethyl-1,5,9-cyclododecatriene were converted into the corresponding unsaturated keto nitriles.",

author = "Isao Shimizu and Munetsugu Fujita and Takayuki Nakajima and Tadashi Sato",

year = "1997",

language = "English",

volume = "1997",

pages = "887--888",

journal = "Synlett",

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publisher = "Georg Thieme Verlag",

number = "8",

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TY - JOUR

T1 - Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins

AU - Shimizu, Isao

AU - Fujita, Munetsugu

AU - Nakajima, Takayuki

AU - Sato, Tadashi

PY - 1997

Y1 - 1997

N2 - Reaction of trisubstituted cyclic olefins with NaN3 in the presence of Cu(OTf)2 upon irradiation under oxygen gave keto nitriles in good yields. 1,5-Dimethyl-1,5-cyclooctadiene and 1,5,9-trimethyl-1,5,9-cyclododecatriene were converted into the corresponding unsaturated keto nitriles.

AB - Reaction of trisubstituted cyclic olefins with NaN3 in the presence of Cu(OTf)2 upon irradiation under oxygen gave keto nitriles in good yields. 1,5-Dimethyl-1,5-cyclooctadiene and 1,5,9-trimethyl-1,5,9-cyclododecatriene were converted into the corresponding unsaturated keto nitriles.

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M3 - Article

AN - SCOPUS:0347422632

SN - 0936-5214

VL - 1997

SP - 887

EP - 888

JO - Synlett

JF - Synlett

IS - 8

ER -

Facile Synthesis of Keto Nitriles by Cu(II)-Promoted Photooxidative Cleavage of Cyclic Olefins

Abstract

ASJC Scopus subject areas

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