Flow orientation in langmuir-blodgett films of a charge-transfer complex (TMTTF)3(C14TCNQ)2

Keiichi Ikegami; Shin Ichi Kuroda; Yuka Tabe; Kazuhiro Saito; Michio Sugi; Mutsuyoshi Matsumoto; Takayoshi Nakamura; Yasujiro Kawabata

doi:10.1143/JJAP.31.1206

Flow orientation in langmuir-blodgett films of a charge-transfer complex (TMTTF)₃(C₁₄TCNQ)₂

Keiichi Ikegami^*, Shin Ichi Kuroda, Yuka Tabe, Kazuhiro Saito, Michio Sugi, Mutsuyoshi Matsumoto, Takayoshi Nakamura, Yasujiro Kawabata

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The occurrence of flow orientation during the deposition of Langmuir-Blodgett films of (TMTTF)₃(C₁₄TCNQ)₂ is shown through studies of in-plane molecular orientation in films deposited by two types of the vertical dipping method, with the substrates parallel and perpendicular to the barrier, using ESR and polarized UV-visible spectroscopies. Larger in-plane anisotropy is observed toward the edge of the substrates, which is consistent with the prediction of the recent theory of flow orientation during the deposition process. Furthermore, in-plane anisotropy in the films deposited by the horizontal lifting method is detected, suggesting the existence of a compression orientation at the air-water interface.

Original language	English
Pages (from-to)	1206-1212
Number of pages	7
Journal	Japanese journal of applied physics
Volume	31
Issue number	4 R
DOIs	https://doi.org/10.1143/JJAP.31.1206
Publication status	Published - 1992 Apr
Externally published	Yes

ASJC Scopus subject areas

Engineering(all)
Physics and Astronomy(all)

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title = "Flow orientation in langmuir-blodgett films of a charge-transfer complex (TMTTF)3(C14TCNQ)2",

abstract = "The occurrence of flow orientation during the deposition of Langmuir-Blodgett films of (TMTTF)3(C14TCNQ)2 is shown through studies of in-plane molecular orientation in films deposited by two types of the vertical dipping method, with the substrates parallel and perpendicular to the barrier, using ESR and polarized UV-visible spectroscopies. Larger in-plane anisotropy is observed toward the edge of the substrates, which is consistent with the prediction of the recent theory of flow orientation during the deposition process. Furthermore, in-plane anisotropy in the films deposited by the horizontal lifting method is detected, suggesting the existence of a compression orientation at the air-water interface.",

author = "Keiichi Ikegami and Kuroda, {Shin Ichi} and Yuka Tabe and Kazuhiro Saito and Michio Sugi and Mutsuyoshi Matsumoto and Takayoshi Nakamura and Yasujiro Kawabata",

year = "1992",

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language = "English",

volume = "31",

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publisher = "Japan Society of Applied Physics",

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T1 - Flow orientation in langmuir-blodgett films of a charge-transfer complex (TMTTF)3(C14TCNQ)2

AU - Ikegami, Keiichi

AU - Kuroda, Shin Ichi

AU - Tabe, Yuka

AU - Saito, Kazuhiro

AU - Sugi, Michio

AU - Matsumoto, Mutsuyoshi

AU - Nakamura, Takayoshi

AU - Kawabata, Yasujiro

PY - 1992/4

Y1 - 1992/4

N2 - The occurrence of flow orientation during the deposition of Langmuir-Blodgett films of (TMTTF)3(C14TCNQ)2 is shown through studies of in-plane molecular orientation in films deposited by two types of the vertical dipping method, with the substrates parallel and perpendicular to the barrier, using ESR and polarized UV-visible spectroscopies. Larger in-plane anisotropy is observed toward the edge of the substrates, which is consistent with the prediction of the recent theory of flow orientation during the deposition process. Furthermore, in-plane anisotropy in the films deposited by the horizontal lifting method is detected, suggesting the existence of a compression orientation at the air-water interface.

AB - The occurrence of flow orientation during the deposition of Langmuir-Blodgett films of (TMTTF)3(C14TCNQ)2 is shown through studies of in-plane molecular orientation in films deposited by two types of the vertical dipping method, with the substrates parallel and perpendicular to the barrier, using ESR and polarized UV-visible spectroscopies. Larger in-plane anisotropy is observed toward the edge of the substrates, which is consistent with the prediction of the recent theory of flow orientation during the deposition process. Furthermore, in-plane anisotropy in the films deposited by the horizontal lifting method is detected, suggesting the existence of a compression orientation at the air-water interface.

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Flow orientation in langmuir-blodgett films of a charge-transfer complex (TMTTF)₃(C₁₄TCNQ)₂

Abstract

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