Formation of a ligand-based mixed-valence cluster triggered by dehydration condensation of semiquinonates with o-phenylenediamines

Ho Chol Chang, Nao Nishida, Susumu Kitagawa*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

A tetrameric [CoII(phenSQ)2]4 with homovalent semiquinonates reacts with o-phenylenediamines to give a ligand-based mixed-valence pentanuclear cluster [{CoII5(phenSQ) 4(phen-Cat)3(THF)3(H2O)}·THF] , containing two differently charged ligands, whose formation is triggered by a dehydration condensation reaction between the semiquinonates and o-phenylenediamines.

Original languageEnglish
Pages (from-to)402-403
Number of pages2
JournalChemistry Letters
Volume34
Issue number3
DOIs
Publication statusPublished - 2005 Mar 5
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry

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