Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate

Dai Mochizuki; Atsushi Shimojima; Kazuyuki Kuroda

doi:10.1021/ja027512t

Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate

Dai Mochizuki, Atsushi Shimojima, Kazuyuki Kuroda^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

Dialkoxydichlorosilanes ((RO)₂SiCl₂, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

Original language	English
Pages (from-to)	12082-12083
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	41
DOIs	https://doi.org/10.1021/ja027512t
Publication status	Published - 2002 Oct 16

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.",

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AU - Mochizuki, Dai

AU - Shimojima, Atsushi

AU - Kuroda, Kazuyuki

PY - 2002/10/16

Y1 - 2002/10/16

N2 - Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

AB - Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route.

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Formation of a new crystalline silicate structure by grafting dialkoxysilyl groups on layered octosilicate

Abstract

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