Forming protective alumina scale for ductile refractory high-entropy alloys via aluminizing

Saad Sheikh, Lu Gan, Xabier Montero, Hideyuki Murakami, Sheng Guo*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)


Refractory high-entropy alloys (RHEAs), or multi-principal-element refractory alloys, have been intensively studied in recent years, due to their attractive potential for ultrahigh-temperature structural applications. One formidable challenge facing the materials development for RHEAs though, is to simultaneously achieve good oxidation resistance and good mechanical properties, which unfortunately often impose contradictory microstructural requirements. So far, there exist no ductile RHEAs that possess reasonable oxidation resistance, and the formation of protective oxide scales such as alumina in them is never seen. Here we report, for the first time, a strategy to form protective alumina scale in ductile RHEAs upon high temperature exposure, using a tailor-designed two-step pack aluminizing process. Very importantly, the oxidation resistance of ductile RHEAs improves tremendously, as evidenced from harsh cyclic oxidation tests, thus providing a huge impetus to push forward the further development of RHEAs, towards ultrahigh-temperature applications.

Original languageEnglish
Article number106838
Publication statusPublished - 2020 Aug


  • Alumina
  • Aluminizing
  • Coating
  • High entropy alloys
  • Oxidation
  • Refractory alloys

ASJC Scopus subject areas

  • General Chemistry
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry


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