Four-electron reduction of dioxygen catalyzed by a decavanadium complex

Eniya Listiani Dewi; Kenichi Oyaizu; Eishun Tsuchida

doi:10.1016/S0020-1693(02)01158-1

Four-electron reduction of dioxygen catalyzed by a decavanadium complex

Eniya Listiani Dewi, Kenichi Oyaizu, Eishun Tsuchida^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The electroreduction of O₂ in acidic aqueous solutions at an electrode modified with a decavanadium cluster [(V=O)₁₀(μ₂-O)₉(μ₃-O) ₃(C₅H₇O₂)₆] (1) revealed that it produces H₂O with four electrons per O₂ molecule near 0.5 V versus SCE. The usefulness of the complex as a reduction catalyst of O₂ with a high selectivity was demonstrated.

Original language	English
Pages (from-to)	316-318
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	342
DOIs	https://doi.org/10.1016/S0020-1693(02)01158-1
Publication status	Published - 2003 Jan 10

Keywords

Decavanadium
Dioxygen
Electrochemistry
Four-electron reduction

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(02)01158-1

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title = "Four-electron reduction of dioxygen catalyzed by a decavanadium complex",

abstract = "The electroreduction of O2 in acidic aqueous solutions at an electrode modified with a decavanadium cluster [(V=O)10(μ2-O)9(μ3-O) 3(C5H7O2)6] (1) revealed that it produces H2O with four electrons per O2 molecule near 0.5 V versus SCE. The usefulness of the complex as a reduction catalyst of O2 with a high selectivity was demonstrated.",

keywords = "Decavanadium, Dioxygen, Electrochemistry, Four-electron reduction",

author = "Dewi, {Eniya Listiani} and Kenichi Oyaizu and Eishun Tsuchida",

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doi = "10.1016/S0020-1693(02)01158-1",

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pages = "316--318",

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AU - Dewi, Eniya Listiani

AU - Oyaizu, Kenichi

AU - Tsuchida, Eishun

PY - 2003/1/10

Y1 - 2003/1/10

N2 - The electroreduction of O2 in acidic aqueous solutions at an electrode modified with a decavanadium cluster [(V=O)10(μ2-O)9(μ3-O) 3(C5H7O2)6] (1) revealed that it produces H2O with four electrons per O2 molecule near 0.5 V versus SCE. The usefulness of the complex as a reduction catalyst of O2 with a high selectivity was demonstrated.

AB - The electroreduction of O2 in acidic aqueous solutions at an electrode modified with a decavanadium cluster [(V=O)10(μ2-O)9(μ3-O) 3(C5H7O2)6] (1) revealed that it produces H2O with four electrons per O2 molecule near 0.5 V versus SCE. The usefulness of the complex as a reduction catalyst of O2 with a high selectivity was demonstrated.

KW - Decavanadium

KW - Dioxygen

KW - Electrochemistry

KW - Four-electron reduction

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VL - 342

SP - 316

EP - 318

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Four-electron reduction of dioxygen catalyzed by a decavanadium complex

Abstract

Keywords

ASJC Scopus subject areas

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