Gas-solid interactions in the hydrogen/single-walled carbon nanotube system

Masashi Shiraishi; Taishi Takenobu; Masafumi Ata

doi:10.1016/S0009-2614(02)01781-5

Gas-solid interactions in the hydrogen/single-walled carbon nanotube system

Masashi Shiraishi^*, Taishi Takenobu, Masafumi Ata

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

Gas-solid interactions between hydrogen and single-walled carbon nanotubes (SWNTs) were investigated using highly purified SWNTs. The activation energy of hydrogen desorption, measured to be 0.21 eV, indicates that hydrogen is physisorbed in the pores and that inter-tube pores have an adsorption potential of about -0.21 eV, which induces hydrogen physisorption at ambient temperature. The total amount of adsorbed hydrogen, about 0.3 wt% at 9 MPa, shows that 38% of the inter-tube sites are occupied. These .ndings are interpreted in terms of the chemical potential of hydrogen and the adsorption potential of the inter-tube pores.

Original language	English
Pages (from-to)	633-636
Number of pages	4
Journal	Chemical Physics Letters
Volume	367
Issue number	5-6
DOIs	https://doi.org/10.1016/S0009-2614(02)01781-5
Publication status	Published - 2003 Jan 10
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics

Access to Document

10.1016/S0009-2614(02)01781-5

Cite this

@article{7df578857aeb47a3bd0d5814d5657476,

title = "Gas-solid interactions in the hydrogen/single-walled carbon nanotube system",

abstract = "Gas-solid interactions between hydrogen and single-walled carbon nanotubes (SWNTs) were investigated using highly purified SWNTs. The activation energy of hydrogen desorption, measured to be 0.21 eV, indicates that hydrogen is physisorbed in the pores and that inter-tube pores have an adsorption potential of about -0.21 eV, which induces hydrogen physisorption at ambient temperature. The total amount of adsorbed hydrogen, about 0.3 wt% at 9 MPa, shows that 38% of the inter-tube sites are occupied. These .ndings are interpreted in terms of the chemical potential of hydrogen and the adsorption potential of the inter-tube pores.",

author = "Masashi Shiraishi and Taishi Takenobu and Masafumi Ata",

year = "2003",

month = jan,

day = "10",

doi = "10.1016/S0009-2614(02)01781-5",

language = "English",

volume = "367",

pages = "633--636",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "5-6",

}

TY - JOUR

T1 - Gas-solid interactions in the hydrogen/single-walled carbon nanotube system

AU - Shiraishi, Masashi

AU - Takenobu, Taishi

AU - Ata, Masafumi

PY - 2003/1/10

Y1 - 2003/1/10

N2 - Gas-solid interactions between hydrogen and single-walled carbon nanotubes (SWNTs) were investigated using highly purified SWNTs. The activation energy of hydrogen desorption, measured to be 0.21 eV, indicates that hydrogen is physisorbed in the pores and that inter-tube pores have an adsorption potential of about -0.21 eV, which induces hydrogen physisorption at ambient temperature. The total amount of adsorbed hydrogen, about 0.3 wt% at 9 MPa, shows that 38% of the inter-tube sites are occupied. These .ndings are interpreted in terms of the chemical potential of hydrogen and the adsorption potential of the inter-tube pores.

AB - Gas-solid interactions between hydrogen and single-walled carbon nanotubes (SWNTs) were investigated using highly purified SWNTs. The activation energy of hydrogen desorption, measured to be 0.21 eV, indicates that hydrogen is physisorbed in the pores and that inter-tube pores have an adsorption potential of about -0.21 eV, which induces hydrogen physisorption at ambient temperature. The total amount of adsorbed hydrogen, about 0.3 wt% at 9 MPa, shows that 38% of the inter-tube sites are occupied. These .ndings are interpreted in terms of the chemical potential of hydrogen and the adsorption potential of the inter-tube pores.

UR - http://www.scopus.com/inward/record.url?scp=0037427733&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037427733&partnerID=8YFLogxK

U2 - 10.1016/S0009-2614(02)01781-5

DO - 10.1016/S0009-2614(02)01781-5

M3 - Article

AN - SCOPUS:0037427733

SN - 0009-2614

VL - 367

SP - 633

EP - 636

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5-6

ER -

Gas-solid interactions in the hydrogen/single-walled carbon nanotube system

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this